New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi, Yusuke Sunada, Hideo Nagashima

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

Original languageEnglish
Pages (from-to)6581-6583
Number of pages3
JournalChemical Communications
Volume47
Issue number23
DOIs
Publication statusPublished - Jun 21 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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