New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi; Yusuke Sunada; Hideo Nagashima

doi:10.1039/c1cc10636h

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi, Yusuke Sunada, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

A heptanuclear iron carbonyl cluster, [Fe₃(CO) ₁₁(μ-H)]₂Fe(DMF)₄ (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

Original language	English
Pages (from-to)	6581-6583
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	23
DOIs	https://doi.org/10.1039/c1cc10636h
Publication status	Published - Jun 21 2011

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc10636h

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abstract = "A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.",

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New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Abstract

All Science Journal Classification (ASJC) codes

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