New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

Hironori Tsutsumi, Yusuke Sunada, Hideo Nagashima

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

Original languageEnglish
Pages (from-to)6581-6583
Number of pages3
JournalChemical Communications
Volume47
Issue number23
DOIs
Publication statusPublished - Jun 21 2011

Fingerprint

Iron
Catalysts
Carbon Monoxide
Benzene
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides. / Tsutsumi, Hironori; Sunada, Yusuke; Nagashima, Hideo.

In: Chemical Communications, Vol. 47, No. 23, 21.06.2011, p. 6581-6583.

Research output: Contribution to journalArticle

Tsutsumi, Hironori ; Sunada, Yusuke ; Nagashima, Hideo. / New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides. In: Chemical Communications. 2011 ; Vol. 47, No. 23. pp. 6581-6583.
@article{f565aa229e10450988e1f6660530e514,
title = "New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides",
abstract = "A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.",
author = "Hironori Tsutsumi and Yusuke Sunada and Hideo Nagashima",
year = "2011",
month = "6",
day = "21",
doi = "10.1039/c1cc10636h",
language = "English",
volume = "47",
pages = "6581--6583",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "23",

}

TY - JOUR

T1 - New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

AU - Tsutsumi, Hironori

AU - Sunada, Yusuke

AU - Nagashima, Hideo

PY - 2011/6/21

Y1 - 2011/6/21

N2 - A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

AB - A heptanuclear iron carbonyl cluster, [Fe3(CO) 11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

UR - http://www.scopus.com/inward/record.url?scp=79958020025&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79958020025&partnerID=8YFLogxK

U2 - 10.1039/c1cc10636h

DO - 10.1039/c1cc10636h

M3 - Article

C2 - 21566808

AN - SCOPUS:79958020025

VL - 47

SP - 6581

EP - 6583

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

ER -