New Dion-Jacobson Phase Three-Layer Perovskite CsBa2Ta3O10 and Its Conversion to Nitrided Ba2Ta3O10 Nanosheets via a Nitridation-Protonation-Intercalation-Exfoliation Route for Water Splitting

Mirabbos Hojamberdiev, Maged F. Bekheet, Ehsan Zahedi, Hajime Wagata, Yuuki Kamei, Kunio Yubuta, Aleksander Gurlo, Nobuhiro Matsushita, Kazunari Domen, Katsuya Teshima

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)


We report on the synthesis of new Dion-Jacobson phase three-layer perovskite CsBa2Ta3O10 crystals by conventional solid-state reaction and fabrication of their nitrided Ba2Ta3O10 nanosheets via a nitridation-protonation-intercalation-exfoliation route for visible-light-driven photocatalytic water splitting application. The two-dimensional crystal structure of CsBa2Ta3O10 refined by the Rietveld refinement method belongs to the simple tetragonal system and consists of corner-shared distorted TaO6 octahedra and Ba cations in cuboctahedral sites forming triple-layer perovskite slabs. The valence and conduction band edge potentials estimated by density functional theory with respect to vacuum scale and normal hydrogen electrode indicate that CsBa2Ta3O10 is a UV-light-active semiconductor that can be used for photocatalytic water splitting and decomposition of organic pollutants. The projected electronic wave functions contour plot of CsBa2Ta3O10 in the (1 0 0) plane exhibited two different Ta-O bonds. The nitridation at 800 °C for 5 h under NH3 atmosphere was found to be suitable for retaining the phase-purity of nitrided CsBa2Ta3O10 crystals. The fabricated nanosheets of nitrided Ba2Ta3O10 with lateral sizes ranging from several hundred nanometers to a few micrometers and height of about 2.3 nm can be applied for visible-light-driven photocatalytic water splitting.

Original languageEnglish
Pages (from-to)2302-2308
Number of pages7
JournalCrystal Growth and Design
Issue number4
Publication statusPublished - Apr 6 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics


Dive into the research topics of 'New Dion-Jacobson Phase Three-Layer Perovskite CsBa<sub>2</sub>Ta<sub>3</sub>O<sub>10</sub> and Its Conversion to Nitrided Ba<sub>2</sub>Ta<sub>3</sub>O<sub>10</sub> Nanosheets via a Nitridation-Protonation-Intercalation-Exfoliation Route for Water Splitting'. Together they form a unique fingerprint.

Cite this