New macrocyclic ligands having discrete metal binding sites

Hisashi Shimakoshi, Hiroki Takemoto, Isao Aritome, Yoshio Hisaeda

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands have two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2+, Cu2+ and Ni2+ to form dimetallic compounds in high yields.

Original languageEnglish
Pages (from-to)4809-4812
Number of pages4
JournalTetrahedron Letters
Volume43
Issue number27
DOIs
Publication statusPublished - Jul 1 2002

Fingerprint

Metals
Binding Sites
Ligands
Condensation reactions
Schiff Bases
Aldehydes
Amines
Ions

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

New macrocyclic ligands having discrete metal binding sites. / Shimakoshi, Hisashi; Takemoto, Hiroki; Aritome, Isao; Hisaeda, Yoshio.

In: Tetrahedron Letters, Vol. 43, No. 27, 01.07.2002, p. 4809-4812.

Research output: Contribution to journalArticle

Shimakoshi, Hisashi ; Takemoto, Hiroki ; Aritome, Isao ; Hisaeda, Yoshio. / New macrocyclic ligands having discrete metal binding sites. In: Tetrahedron Letters. 2002 ; Vol. 43, No. 27. pp. 4809-4812.
@article{7684324687d94874aa5ce0c2cd9e1246,
title = "New macrocyclic ligands having discrete metal binding sites",
abstract = "New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands have two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2+, Cu2+ and Ni2+ to form dimetallic compounds in high yields.",
author = "Hisashi Shimakoshi and Hiroki Takemoto and Isao Aritome and Yoshio Hisaeda",
year = "2002",
month = "7",
day = "1",
doi = "10.1016/S0040-4039(02)00923-1",
language = "English",
volume = "43",
pages = "4809--4812",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "27",

}

TY - JOUR

T1 - New macrocyclic ligands having discrete metal binding sites

AU - Shimakoshi, Hisashi

AU - Takemoto, Hiroki

AU - Aritome, Isao

AU - Hisaeda, Yoshio

PY - 2002/7/1

Y1 - 2002/7/1

N2 - New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands have two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2+, Cu2+ and Ni2+ to form dimetallic compounds in high yields.

AB - New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands have two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2+, Cu2+ and Ni2+ to form dimetallic compounds in high yields.

UR - http://www.scopus.com/inward/record.url?scp=0036644109&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036644109&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(02)00923-1

DO - 10.1016/S0040-4039(02)00923-1

M3 - Article

AN - SCOPUS:0036644109

VL - 43

SP - 4809

EP - 4812

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 27

ER -