New macrocyclic ligands having discrete metal binding sites

Hisashi Shimakoshi, Hiroki Takemoto, Isao Aritome, Yoshio Hisaeda

    Research output: Contribution to journalArticlepeer-review

    59 Citations (Scopus)

    Abstract

    New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands have two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2+, Cu2+ and Ni2+ to form dimetallic compounds in high yields.

    Original languageEnglish
    Pages (from-to)4809-4812
    Number of pages4
    JournalTetrahedron Letters
    Volume43
    Issue number27
    DOIs
    Publication statusPublished - Jul 1 2002

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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