New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structures

Charles F. Baker; Marten G. Barker; Claire Wilson; Duncan H. Gregory

doi:10.1039/b316558b

New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structures

Charles F. Baker, Marten G. Barker, Claire Wilson, Duncan H. Gregory

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

New molybdenum(vi) nitride oxides were synthesised by the reaction of strontium nitride and calcium nitride with molybdenum foil at high temperature in sealed stainless steel crucibles. The reactions yielded single crystalline products determined by X-ray diffraction to form complex structures in the triclinic space group P1 (no. 2). The mixed alkaline earth compounds with composition Ca₃₈Sr₁₃[MoN₄]₁₂N₈O₃and Ca₃₆Sr₁₅[MoN₄]₁₂N₈O₃are isostructural with the quaternary nitride oxides Sr₅₁[WN₄]₁₂N₈O₃and Ca₅₁[WN₄]₁₂N₈O₃. The structures contain isolated [MoN₄]⁶⁻tetrahedra, partially disordered alkaline earth cations and an ordered sublattice of N³⁻and O²⁻anions. Oxide anions are coordinated only to the alkaline earth metals. The title compounds are the first mixed alkaline earth metal nitride oxides.

Original language	English
Pages (from-to)	1298-1303
Number of pages	6
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	4
Issue number	9
DOIs	https://doi.org/10.1039/b316558b
Publication status	Published - Apr 23 2004
Externally published	Yes

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Chemistry(all)

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10.1039/b316558b

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title = "New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structures",

abstract = "New molybdenum(vi) nitride oxides were synthesised by the reaction of strontium nitride and calcium nitride with molybdenum foil at high temperature in sealed stainless steel crucibles. The reactions yielded single crystalline products determined by X-ray diffraction to form complex structures in the triclinic space group P1 (no. 2). The mixed alkaline earth compounds with composition Ca38Sr13[MoN4]12N8O3and Ca36Sr15[MoN4]12N8O3are isostructural with the quaternary nitride oxides Sr51[WN4]12N8O3and Ca51[WN4]12N8O3. The structures contain isolated [MoN4]6−tetrahedra, partially disordered alkaline earth cations and an ordered sublattice of N3−and O2−anions. Oxide anions are coordinated only to the alkaline earth metals. The title compounds are the first mixed alkaline earth metal nitride oxides.",

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AU - Baker, Charles F.

AU - Barker, Marten G.

AU - Wilson, Claire

AU - Gregory, Duncan H.

PY - 2004/4/23

Y1 - 2004/4/23

N2 - New molybdenum(vi) nitride oxides were synthesised by the reaction of strontium nitride and calcium nitride with molybdenum foil at high temperature in sealed stainless steel crucibles. The reactions yielded single crystalline products determined by X-ray diffraction to form complex structures in the triclinic space group P1 (no. 2). The mixed alkaline earth compounds with composition Ca38Sr13[MoN4]12N8O3and Ca36Sr15[MoN4]12N8O3are isostructural with the quaternary nitride oxides Sr51[WN4]12N8O3and Ca51[WN4]12N8O3. The structures contain isolated [MoN4]6−tetrahedra, partially disordered alkaline earth cations and an ordered sublattice of N3−and O2−anions. Oxide anions are coordinated only to the alkaline earth metals. The title compounds are the first mixed alkaline earth metal nitride oxides.

AB - New molybdenum(vi) nitride oxides were synthesised by the reaction of strontium nitride and calcium nitride with molybdenum foil at high temperature in sealed stainless steel crucibles. The reactions yielded single crystalline products determined by X-ray diffraction to form complex structures in the triclinic space group P1 (no. 2). The mixed alkaline earth compounds with composition Ca38Sr13[MoN4]12N8O3and Ca36Sr15[MoN4]12N8O3are isostructural with the quaternary nitride oxides Sr51[WN4]12N8O3and Ca51[WN4]12N8O3. The structures contain isolated [MoN4]6−tetrahedra, partially disordered alkaline earth cations and an ordered sublattice of N3−and O2−anions. Oxide anions are coordinated only to the alkaline earth metals. The title compounds are the first mixed alkaline earth metal nitride oxides.

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New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structures

Abstract

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