New oxalate-bridged CrIII-MnII polymeric network incorporating a spin-crossover [Co(terpy)2]2+ cation

Hui Zhong Kou, Osamu Sato

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23 Citations (Scopus)


The reaction of Mn2+ with [Cr(ox)3]3- in the presence of the spin-crossover [Co(terpy)2]2+ cation gives rise to a 1D [Co(terpy)2][Mn(H2O)ClCr(ox) 3]·H2O·0.5MeOH (1) or a 2D [Co(terpy) 2][Mn(H2O)Cr(ox)3]2·5H 2O·0.5MeOH (2). The trimetallic complexes display dominant ferromagnetic behavior, and spin-crossover of [Co(terpy)2] 2+ is suppressed by the chemical pressure of the polymeric oxalate-bridged network.

Original languageEnglish
Pages (from-to)9513-9515
Number of pages3
JournalInorganic chemistry
Issue number23
Publication statusPublished - Nov 12 2007

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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