New water-soluble host molecules derived from calix[6]arene

Seiji Shinkai; Seiichi Mori; Takayuki Tsubaki; Takaaki Sone; Osamu Manabe

doi:10.1016/S0040-4039(01)81592-6

New water-soluble host molecules derived from calix[6]arene

Seiji Shinkai, Seiichi Mori, Takayuki Tsubaki, Takaaki Sone, Osamu Manabe

Research output: Contribution to journal › Article › peer-review

203 Citations (Scopus)

Abstract

4-Sulfonate derivatives of calix[6]arene and O-n-hexylcalix[6]arene (1a and 1b, respectively) were synthesized. Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix-[6]arene can accept a naphthalene molecule but not a pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water. This is the first example for water-soluble host molecules derived from calix[6]arene.

Original language	English
Pages (from-to)	5315-5318
Number of pages	4
Journal	Tetrahedron Letters
Volume	25
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(01)81592-6
Publication status	Published - 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)81592-6

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title = "New water-soluble host molecules derived from calix[6]arene",

abstract = "4-Sulfonate derivatives of calix[6]arene and O-n-hexylcalix[6]arene (1a and 1b, respectively) were synthesized. Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix-[6]arene can accept a naphthalene molecule but not a pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water. This is the first example for water-soluble host molecules derived from calix[6]arene.",

author = "Seiji Shinkai and Seiichi Mori and Takayuki Tsubaki and Takaaki Sone and Osamu Manabe",

year = "1984",

doi = "10.1016/S0040-4039(01)81592-6",

language = "English",

volume = "25",

pages = "5315--5318",

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T1 - New water-soluble host molecules derived from calix[6]arene

AU - Shinkai, Seiji

AU - Mori, Seiichi

AU - Tsubaki, Takayuki

AU - Sone, Takaaki

AU - Manabe, Osamu

PY - 1984

Y1 - 1984

N2 - 4-Sulfonate derivatives of calix[6]arene and O-n-hexylcalix[6]arene (1a and 1b, respectively) were synthesized. Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix-[6]arene can accept a naphthalene molecule but not a pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water. This is the first example for water-soluble host molecules derived from calix[6]arene.

AB - 4-Sulfonate derivatives of calix[6]arene and O-n-hexylcalix[6]arene (1a and 1b, respectively) were synthesized. Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix-[6]arene can accept a naphthalene molecule but not a pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water. This is the first example for water-soluble host molecules derived from calix[6]arene.

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DO - 10.1016/S0040-4039(01)81592-6

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EP - 5318

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

New water-soluble host molecules derived from calix[6]arene

Abstract

All Science Journal Classification (ASJC) codes

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