Ni-Fe cermet as stable anode for direct CH4 type SOFC

Hao Zhong; Hiroshige Matsumoto; Tatsumi Ishihara

doi:10.1149/1.3205765

Ni-Fe cermet as stable anode for direct CH₄ type SOFC

Hao Zhong, Hiroshige Matsumoto, Tatsumi Ishihara

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Citations (Scopus)

Abstract

Ni-Fe/La_0.9Sr_0.1Ga_0.8Mg _0.2O₃ (LSGM) (90:10) cermet anode for direct CH ₄ SOFC was studied. Among the various cermets studied, it was found that Ni-Fe/LSGM exhibits the superior catalytic activity for CH₄ oxidation and also stability in CH₄, and so the carbon deposition was highly suppressed. This improvement could be explained by an increase in basic property of LSGM. The further kinetic study was performed and this cermet anode shows almost zero P_CH4 dependence of anodic overpotential. Therefore, the rate-determining step of CH₄ electrochemical oxidation on this cermet seems to be the charge transfer process due to a high surface activity of NiFe-LSGM catalyst.

Original language	English
Title of host publication	ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)
Pages	2161-2168
Number of pages	8
Edition	2 PART 3
DOIs	https://doi.org/10.1149/1.3205765
Publication status	Published - 2009
Event	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting - Vienna, Austria Duration: Oct 4 2009 → Oct 9 2009

Publication series

Name	ECS Transactions
Number	2 PART 3
Volume	25
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Other

Other	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting
Country/Territory	Austria
City	Vienna
Period	10/4/09 → 10/9/09

All Science Journal Classification (ASJC) codes

Engineering(all)

Access to Document

10.1149/1.3205765

Cite this

Zhong, H, Matsumoto, H & Ishihara, T 2009, Ni-Fe cermet as stable anode for direct CH₄ type SOFC. in ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI). 2 PART 3 edn, ECS Transactions, no. 2 PART 3, vol. 25, pp. 2161-2168, 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting, Vienna, Austria, 10/4/09. https://doi.org/10.1149/1.3205765

@inproceedings{49bbb996a15045e98c9a5e0a58cafd5e,

title = "Ni-Fe cermet as stable anode for direct CH4 type SOFC",

abstract = "Ni-Fe/La0.9Sr0.1Ga0.8Mg 0.2O3 (LSGM) (90:10) cermet anode for direct CH 4 SOFC was studied. Among the various cermets studied, it was found that Ni-Fe/LSGM exhibits the superior catalytic activity for CH4 oxidation and also stability in CH4, and so the carbon deposition was highly suppressed. This improvement could be explained by an increase in basic property of LSGM. The further kinetic study was performed and this cermet anode shows almost zero PCH4 dependence of anodic overpotential. Therefore, the rate-determining step of CH4 electrochemical oxidation on this cermet seems to be the charge transfer process due to a high surface activity of NiFe-LSGM catalyst.",

author = "Hao Zhong and Hiroshige Matsumoto and Tatsumi Ishihara",

year = "2009",

doi = "10.1149/1.3205765",

language = "English",

isbn = "9781566777391",

series = "ECS Transactions",

number = "2 PART 3",

pages = "2161--2168",

booktitle = "ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)",

edition = "2 PART 3",

note = "11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting ; Conference date: 04-10-2009 Through 09-10-2009",

}

TY - GEN

T1 - Ni-Fe cermet as stable anode for direct CH4 type SOFC

AU - Zhong, Hao

AU - Matsumoto, Hiroshige

AU - Ishihara, Tatsumi

PY - 2009

Y1 - 2009

N2 - Ni-Fe/La0.9Sr0.1Ga0.8Mg 0.2O3 (LSGM) (90:10) cermet anode for direct CH 4 SOFC was studied. Among the various cermets studied, it was found that Ni-Fe/LSGM exhibits the superior catalytic activity for CH4 oxidation and also stability in CH4, and so the carbon deposition was highly suppressed. This improvement could be explained by an increase in basic property of LSGM. The further kinetic study was performed and this cermet anode shows almost zero PCH4 dependence of anodic overpotential. Therefore, the rate-determining step of CH4 electrochemical oxidation on this cermet seems to be the charge transfer process due to a high surface activity of NiFe-LSGM catalyst.

AB - Ni-Fe/La0.9Sr0.1Ga0.8Mg 0.2O3 (LSGM) (90:10) cermet anode for direct CH 4 SOFC was studied. Among the various cermets studied, it was found that Ni-Fe/LSGM exhibits the superior catalytic activity for CH4 oxidation and also stability in CH4, and so the carbon deposition was highly suppressed. This improvement could be explained by an increase in basic property of LSGM. The further kinetic study was performed and this cermet anode shows almost zero PCH4 dependence of anodic overpotential. Therefore, the rate-determining step of CH4 electrochemical oxidation on this cermet seems to be the charge transfer process due to a high surface activity of NiFe-LSGM catalyst.

UR - http://www.scopus.com/inward/record.url?scp=77649122599&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77649122599&partnerID=8YFLogxK

U2 - 10.1149/1.3205765

DO - 10.1149/1.3205765

M3 - Conference contribution

AN - SCOPUS:77649122599

SN - 9781566777391

T3 - ECS Transactions

SP - 2161

EP - 2168

BT - ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)

T2 - 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting

Y2 - 4 October 2009 through 9 October 2009

ER -