NMR studies of ordered structures and valence states in the successive valence-transition system EuPtP

T. Mito, K. Nishitani, T. Koyama, H. Muta, T. Maruyama, G. Pristáš, K. Ueda, T. Kohara, A. Mitsuda, M. Sugishima, H. Wada

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Abstract

We have studied EuPtP, which undergoes two successive valence transitions at TA∼240 K and TB∼200 K by P31-nuclear magnetic resonance (NMR) measurements. From the analysis of NMR spectra, we obtained plausible ordered structures and Eu valence states in three phases divided by TA and TB. These ordered structures well explain observed inequivalent P sites and the intensity ratio of the NMR spectra arising from these P sites. The results are also in good accordance with mean Eu valence measured by the x-ray absorption spectroscopy. We also discuss Eu 4f states and the origin of the transitions from the measurements of nuclear spin lattice relaxation rate and hyperfine coupling constant.

Original languageEnglish
Article number195106
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume90
Issue number19
DOIs
Publication statusPublished - Nov 4 2014

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Nuclear magnetic resonance
valence
nuclear magnetic resonance
Magnetic resonance measurement
Spin-lattice relaxation
Absorption spectroscopy
x ray absorption
spin-lattice relaxation
nuclear spin
x ray spectroscopy
absorption spectroscopy
X rays

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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NMR studies of ordered structures and valence states in the successive valence-transition system EuPtP. / Mito, T.; Nishitani, K.; Koyama, T.; Muta, H.; Maruyama, T.; Pristáš, G.; Ueda, K.; Kohara, T.; Mitsuda, A.; Sugishima, M.; Wada, H.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 90, No. 19, 195106, 04.11.2014.

Research output: Contribution to journalArticle

Mito, T. ; Nishitani, K. ; Koyama, T. ; Muta, H. ; Maruyama, T. ; Pristáš, G. ; Ueda, K. ; Kohara, T. ; Mitsuda, A. ; Sugishima, M. ; Wada, H. / NMR studies of ordered structures and valence states in the successive valence-transition system EuPtP. In: Physical Review B - Condensed Matter and Materials Physics. 2014 ; Vol. 90, No. 19.
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AU - Mito, T.

AU - Nishitani, K.

AU - Koyama, T.

AU - Muta, H.

AU - Maruyama, T.

AU - Pristáš, G.

AU - Ueda, K.

AU - Kohara, T.

AU - Mitsuda, A.

AU - Sugishima, M.

AU - Wada, H.

PY - 2014/11/4

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