[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

Ken Sakai, Yuko Tanaka, Taro Tsubomura

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

Original languageEnglish
Pages (from-to)541-543
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number3
DOIs
Publication statusPublished - Mar 15 1996
Externally publishedYes

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ethylenediamine
Platinum
Ligands
Atoms
Chelation
Amines
Hydrogen
Hydrogen bonds
Salts
Ions
tetrachloroplatinate
platinum tetrachloride

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

@article{e93870cd104d44ebbaeb8d5a1486e6a7,
title = "[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate",
abstract = "The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) {\AA}.",
author = "Ken Sakai and Yuko Tanaka and Taro Tsubomura",
year = "1996",
month = "3",
day = "15",
doi = "10.1107/S0108270195011413",
language = "English",
volume = "52",
pages = "541--543",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "3",

}

TY - JOUR

T1 - [N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

AU - Sakai, Ken

AU - Tanaka, Yuko

AU - Tsubomura, Taro

PY - 1996/3/15

Y1 - 1996/3/15

N2 - The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

AB - The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

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U2 - 10.1107/S0108270195011413

DO - 10.1107/S0108270195011413

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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