[N,N′-bis(2-aminoethyl-κN)-N,N′-bis(2-ammonioethyl) ethylenediamine-κ2N,N′]-platinum(II) bis(tetrachloroplatinate) trihydrate

Ken Sakai, Yuko Tanaka, Taro Tsubomura

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The reaction between K2PtCl4 and penten [N,N,N′,N′-tetrakis(2-aminoethyl)ethylenediamine] gave a Magnus-type double salt, [Pt(C10H30N6)][PtCl4] 2.3H2O, in which the diprotonated penten ligand (pentenH2) serves as a tetradentate chelating ligand. The complex involves an ion pair, {[Pt(pentenH2)][PtCl4]}2+. These two mononuclear units have an attractive interaction for each other, with several hydrogen bonds formed between the amine groups and Cl atoms. The two Pt atoms are shifted out of their ideal coordination planes towards each other and the Pt⋯Pt distance within this unit is 3.414 (3) Å.

Original languageEnglish
Pages (from-to)541-543
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number3
DOIs
Publication statusPublished - Mar 15 1996
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

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