Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

Daisuke Noda, Atsushi Tahara, Yusuke Sunada, Hideo Nagashima

Research output: Contribution to journalArticle

82 Citations (Scopus)

Abstract

A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >103) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.

Original languageEnglish
Pages (from-to)2480-2483
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number8
DOIs
Publication statusPublished - Mar 2 2016

Fingerprint

Hydrosilylation
Cyanides
Alkenes
Cobalt
Olefins
Iron
Metals
Catalysts
Styrene
Ethers
Silicones
Catalyst selectivity
Chemical modification
Ligands
Catalyst activity
Derivatives

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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abstract = "A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >103) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.",
author = "Daisuke Noda and Atsushi Tahara and Yusuke Sunada and Hideo Nagashima",
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AU - Noda, Daisuke

AU - Tahara, Atsushi

AU - Sunada, Yusuke

AU - Nagashima, Hideo

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Y1 - 2016/3/2

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AB - A mixture of an iron or a cobalt carboxylate and an isocyanide ligand catalyzed the hydrosilylation of alkenes with hydrosiloxanes with high efficiency (TON >103) and high selectivity. The Fe catalyst showed excellent activity for hydrosilylation of styrene derivatives, whereas the Co catalyst was widely effective in reaction of alkenes. Both of them catalyzed the reaction with allylic ethers. Chemical modification and cross-linking of silicones were achieved by choosing the right catalyst and reaction conditions.

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