Nonlinear dielectric relaxation spectra calculated with a free rotation model of the dipole moment

Yasuyuki Kimura, Reinosuke Hayakawa

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Nonlinear dielectric relaxation spectroscopy has recently been utilized to investigate the details of electrical dynamics in a variety of substances. The nonlinear spectra obtained have usually been analyzed in terms of a phenomenological nonlinear response theory proposed by Nakada. In this paper, to check the validity of the phenomenological theory, the dielectric relaxation spectra of first and third orders are calculated from the molecular theory based on a free rotation model of the dipole moment. The after-effect function of exponential decay type assumed in the phenomenological theory is not applicable to the free rotation model. The validity of phenomenological expressions for nonlinear spectra as approximate or semiempirical formulas is discussed in detail.

Original languageEnglish
Pages (from-to)3387-3391
Number of pages5
JournalJapanese Journal of Applied Physics
Volume31
Issue number10 R
DOIs
Publication statusPublished - 1992
Externally publishedYes

Fingerprint

Dielectric relaxation
Dipole moment
dipole moments
molecular theory
Spectroscopy
decay
spectroscopy

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Nonlinear dielectric relaxation spectra calculated with a free rotation model of the dipole moment. / Kimura, Yasuyuki; Hayakawa, Reinosuke.

In: Japanese Journal of Applied Physics, Vol. 31, No. 10 R, 1992, p. 3387-3391.

Research output: Contribution to journalArticle

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