Abstract
Radical polyaddition of bis(α-trifluoromethyl-β, β-difluorovinyl) terephthalate [CF2=C (CF3)OCOC6H4COOC(CF3) =CF2] (BFP) with 18-crown-6 to produce fluorinated polymer bearing crown ether moiety in main chain is described. Prior to polyaddition, the model reaction of 2-benzoxypentafluoropropene [CF2=C(CF3)OCOC6H5] (BPFP) with 18-crown-6 was investigated to afford suitable reactions condition for polyaddition. The polyaddition of BFP with 18-crown-6 yielded a soluble polymer bearing Mn=5.5×104 with unimodal molecular weight distribution after purification by reprecipitation with cold ethanol.
Original language | English |
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Pages (from-to) | 197-201 |
Number of pages | 5 |
Journal | Journal of Fluorine Chemistry |
Volume | 124 |
Issue number | 2 |
DOIs | |
Publication status | Published - Dec 3 2003 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Environmental Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry