Novel lithium ion conductive polymers and their conductive mechanism from the view point of complex chemistry

Hitoshi Yamamoto; Daiki Tabata; Syuichi Urabe; Taka Aki Okamura; Norikazu Ueyama; Akira Sato; Shin Nishimura

Novel lithium ion conductive polymers and their conductive mechanism from the view point of complex chemistry

Hitoshi Yamamoto, Daiki Tabata, Syuichi Urabe, Taka Aki Okamura, Norikazu Ueyama, Akira Sato, Shin Nishimura

Research output: Contribution to conference › Paper › peer-review

Abstract

We have designed novel solid polymer electrolytes which transfer the lithium ion by the rotational motion of the side-chain functional groups. The activation energy of rotational motion is thought to be over ten times lower than the segmental motion of the polymer main chain. The methoxy substituents work as the coordination cites or ligands to the lithium ions. The Arrhenius plots of ion conductivity of our polymer electrolyte determined by AC impedance method indicate that the activation energy of ion conductivity in our polymer is quite lower ≒5 kcal/mol) than conventional PEO (ca. 40kcal/mol). Further information about the mechanism of ion conductivity in this polymer will be discussed.

Original language	English
Pages	4559-4560
Number of pages	2
Publication status	Published - Dec 1 2005
Externally published	Yes
Event	54th SPSJ Symposium on Macromolecules - Yamagata, Japan Duration: Sep 20 2005 → Sep 22 2005

Other

Other	54th SPSJ Symposium on Macromolecules
Country/Territory	Japan
City	Yamagata
Period	9/20/05 → 9/22/05

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

Novel lithium ion conductive polymers and their conductive mechanism from the view point of complex chemistry. / Yamamoto, Hitoshi; Tabata, Daiki; Urabe, Syuichi; Okamura, Taka Aki; Ueyama, Norikazu; Sato, Akira; Nishimura, Shin.

2005. 4559-4560 Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.

Research output: Contribution to conference › Paper › peer-review

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abstract = "We have designed novel solid polymer electrolytes which transfer the lithium ion by the rotational motion of the side-chain functional groups. The activation energy of rotational motion is thought to be over ten times lower than the segmental motion of the polymer main chain. The methoxy substituents work as the coordination cites or ligands to the lithium ions. The Arrhenius plots of ion conductivity of our polymer electrolyte determined by AC impedance method indicate that the activation energy of ion conductivity in our polymer is quite lower ≒5 kcal/mol) than conventional PEO (ca. 40kcal/mol). Further information about the mechanism of ion conductivity in this polymer will be discussed.",

author = "Hitoshi Yamamoto and Daiki Tabata and Syuichi Urabe and Okamura, {Taka Aki} and Norikazu Ueyama and Akira Sato and Shin Nishimura",

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T1 - Novel lithium ion conductive polymers and their conductive mechanism from the view point of complex chemistry

AU - Yamamoto, Hitoshi

AU - Tabata, Daiki

AU - Urabe, Syuichi

AU - Okamura, Taka Aki

AU - Ueyama, Norikazu

AU - Sato, Akira

AU - Nishimura, Shin

PY - 2005/12/1

Y1 - 2005/12/1

N2 - We have designed novel solid polymer electrolytes which transfer the lithium ion by the rotational motion of the side-chain functional groups. The activation energy of rotational motion is thought to be over ten times lower than the segmental motion of the polymer main chain. The methoxy substituents work as the coordination cites or ligands to the lithium ions. The Arrhenius plots of ion conductivity of our polymer electrolyte determined by AC impedance method indicate that the activation energy of ion conductivity in our polymer is quite lower ≒5 kcal/mol) than conventional PEO (ca. 40kcal/mol). Further information about the mechanism of ion conductivity in this polymer will be discussed.

AB - We have designed novel solid polymer electrolytes which transfer the lithium ion by the rotational motion of the side-chain functional groups. The activation energy of rotational motion is thought to be over ten times lower than the segmental motion of the polymer main chain. The methoxy substituents work as the coordination cites or ligands to the lithium ions. The Arrhenius plots of ion conductivity of our polymer electrolyte determined by AC impedance method indicate that the activation energy of ion conductivity in our polymer is quite lower ≒5 kcal/mol) than conventional PEO (ca. 40kcal/mol). Further information about the mechanism of ion conductivity in this polymer will be discussed.

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M3 - Paper

AN - SCOPUS:33645557607

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T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Novel lithium ion conductive polymers and their conductive mechanism from the view point of complex chemistry

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All Science Journal Classification (ASJC) codes

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