Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker: Effective amplification of a binding signal through positive homotropic allosterism

Atsushi Sugasaki, Masato Ikeda, Masayuki Takeuchi, Seiji Shinkai

Research output: Contribution to journal › Article

84 Citations (Scopus)

Abstract

The effective binding of oligosaccharides with large association constants (K=105 - 106M-2) is achieved with the novel scaffold 1. The binding takes place in aqueous media according to a positive homotropic allosterism to form 1:2 1:saccharide complexes.

Original languageEnglish
Pages (from-to)3839-3842
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number21
DOIs
Publication statusPublished - Nov 3 2000

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Cerium
Oligosaccharides
Scaffolds
Amplification
5-demethylbupranolol

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker : Effective amplification of a binding signal through positive homotropic allosterism. / Sugasaki, Atsushi; Ikeda, Masato; Takeuchi, Masayuki; Shinkai, Seiji.

In: Angewandte Chemie - International Edition, Vol. 39, No. 21, 03.11.2000, p. 3839-3842.

Research output: Contribution to journal › Article

Sugasaki, A, Ikeda, M, Takeuchi, M & Shinkai, S 2000, 'Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker: Effective amplification of a binding signal through positive homotropic allosterism', Angewandte Chemie - International Edition, vol. 39, no. 21, pp. 3839-3842. https://doi.org/10.1002/1521-3773(20001103)39:21<3839::AID-ANIE3839>3.0.CO;2-2
Sugasaki A, Ikeda M, Takeuchi M, Shinkai S. Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker: Effective amplification of a binding signal through positive homotropic allosterism. Angewandte Chemie - International Edition. 2000 Nov 3;39(21):3839-3842. https://doi.org/10.1002/1521-3773(20001103)39:21<3839::AID-ANIE3839>3.0.CO;2-2
Sugasaki, Atsushi ; Ikeda, Masato ; Takeuchi, Masayuki ; Shinkai, Seiji. / Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker : Effective amplification of a binding signal through positive homotropic allosterism. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 21. pp. 3839-3842.
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