Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker: Effective amplification of a binding signal through positive homotropic allosterism

Atsushi Sugasaki, Masato Ikeda, Masayuki Takeuchi, Seiji Shinkai

Research output: Contribution to journalArticle

84 Citations (Scopus)

Abstract

The effective binding of oligosaccharides with large association constants (K=105 - 106M-2) is achieved with the novel scaffold 1. The binding takes place in aqueous media according to a positive homotropic allosterism to form 1:2 1:saccharide complexes.

Original languageEnglish
Pages (from-to)3839-3842
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number21
DOIs
Publication statusPublished - Nov 3 2000

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Cerium
Oligosaccharides
Scaffolds
Amplification
5-demethylbupranolol

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Novel oligosaccharide binding to the cerium(IV) bis(porphyrinate) double decker : Effective amplification of a binding signal through positive homotropic allosterism. / Sugasaki, Atsushi; Ikeda, Masato; Takeuchi, Masayuki; Shinkai, Seiji.

In: Angewandte Chemie - International Edition, Vol. 39, No. 21, 03.11.2000, p. 3839-3842.

Research output: Contribution to journalArticle

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