Novel structural and magnetic properties of a 1-D iron(II)-manganese(II) LIESST compound bridged by cyanide

Shinya Hayami; Gergely Juhász; Yonezo Maeda; Toshihiko Yokoyama; Osamu Sato

doi:10.1021/ic0509837

Novel structural and magnetic properties of a 1-D iron(II)-manganese(II) LIESST compound bridged by cyanide

Shinya Hayami, Gergely Juhász, Yonezo Maeda, Toshihiko Yokoyama, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article

34 Citations (Scopus)

Abstract

The 1-D compound [Fe(L)(CN)₂][Mn(hfac)₂] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.

Original language	English
Pages (from-to)	7289-7291
Number of pages	3
Journal	Inorganic chemistry
Volume	44
Issue number	21
DOIs	https://doi.org/10.1021/ic0509837
Publication status	Published - Oct 17 2005

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic0509837

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title = "Novel structural and magnetic properties of a 1-D iron(II)-manganese(II) LIESST compound bridged by cyanide",

abstract = "The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.",

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AU - Juhász, Gergely

AU - Maeda, Yonezo

AU - Yokoyama, Toshihiko

AU - Sato, Osamu

PY - 2005/10/17

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N2 - The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.

AB - The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.

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