Nucleophilic substitution reaction at the nitrogen of arylsulfonamides with phosphide anion

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Abstract

A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.

Original languageEnglish
Pages (from-to)19358-19361
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number47
DOIs
Publication statusPublished - Nov 28 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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