Numerical simulation of concentration over-voltage in a polymer electrolyte fuel cell under low-hydrogen conditions

Takahisa Yamamoto, Kazuhiro Ishimaru, Kahar Osman, Mohamad Ikhwan Kori, Ahmad Zaharan Khudzari, Ishkrizat Taib, Tsuyoshi Yamamoto

Research output: Contribution to journalArticle

Abstract

This article elucidates the effect of low hydrogen concentration fuel gas on polymer electrolyte fuel cell (PEFC) performance, with particular emphasis on the transport of chemical species in the anode separator channel and the electrochemical reactions. A numerical simulation model for PEFCs was developed; the model combined a computational fluid dynamics model for mass transfer in the anode separator and the gas diffusion layer (GDL) as well as a PEFC electrochemical reaction model taking into account the activation, concentration, and resistance over-voltages. The emphasis in this study is placed on obtaining a basic understanding of how three-dimensional flow and low-hydrogen fuel transport phenomena in the anode separator channel impact the electrochemical processes occurring in PEFCs. Comparison of the numerical simulation results with experimental data indicates that the performance degradation in PEFCs is negligible for hydrogen concentrations over 30%, whereas it becomes significant for concentrations below 10%. Furthermore, the numerical simulation results show that controlling the fuel supply flow rate stimulates hydrogen transport in the GDL and the catalyst layer, which consequently enhances PEFC performance under low-hydrogen conditions.

Original languageEnglish
Pages (from-to)88-94
Number of pages7
JournalInternational Journal of Integrated Engineering
Volume10
Issue number4
Publication statusPublished - Jan 1 2018

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Electrolytes
Fuel cells
Hydrogen
Polymers
Separators
Anodes
Diffusion in gases
Computer simulation
Electric potential
Hydrogen fuels
Gas fuels
Dynamic models
Computational fluid dynamics
Mass transfer
Chemical activation
Flow rate
Degradation
Catalysts

All Science Journal Classification (ASJC) codes

  • Civil and Structural Engineering
  • Materials Science (miscellaneous)
  • Mechanics of Materials
  • Mechanical Engineering
  • Industrial and Manufacturing Engineering
  • Electrical and Electronic Engineering

Cite this

Numerical simulation of concentration over-voltage in a polymer electrolyte fuel cell under low-hydrogen conditions. / Yamamoto, Takahisa; Ishimaru, Kazuhiro; Osman, Kahar; Kori, Mohamad Ikhwan; Khudzari, Ahmad Zaharan; Taib, Ishkrizat; Yamamoto, Tsuyoshi.

In: International Journal of Integrated Engineering, Vol. 10, No. 4, 01.01.2018, p. 88-94.

Research output: Contribution to journalArticle

Yamamoto, Takahisa ; Ishimaru, Kazuhiro ; Osman, Kahar ; Kori, Mohamad Ikhwan ; Khudzari, Ahmad Zaharan ; Taib, Ishkrizat ; Yamamoto, Tsuyoshi. / Numerical simulation of concentration over-voltage in a polymer electrolyte fuel cell under low-hydrogen conditions. In: International Journal of Integrated Engineering. 2018 ; Vol. 10, No. 4. pp. 88-94.
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