On the nature of strong hydrogen atom trapping inside Pd nanoparticles

Hirokazu Kobayashi, Miho Yamauchi, Hiroshi Kitagawa, Yoshiki Kubota, Kenichi Kato, Masaki Takata

    Research output: Contribution to journalArticlepeer-review

    142 Citations (Scopus)

    Abstract

    We have investigated the hydrogen absorption/desorption hysteresis by means of in situ powder X-ray diffraction (XRD) and solid-state 2H NMR to clarify the location of hydrogen, surface or body, and its chemical form, molecular, atomic, or as hydride. The present results point out that strongly trapped hydrogen atoms exist inside the Pd nanoparticles due to a strong Pd-H bond formation and are stabilized in the lattice of Pd nanoparticles, compared to bulk Pd.

    Original languageEnglish
    Pages (from-to)1828-1829
    Number of pages2
    JournalJournal of the American Chemical Society
    Volume130
    Issue number6
    DOIs
    Publication statusPublished - Feb 13 2008

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)
    • Biochemistry
    • Colloid and Surface Chemistry

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