On the nature of strong hydrogen atom trapping inside Pd nanoparticles

Hirokazu Kobayashi, Miho Yamauchi, Hiroshi Kitagawa, Yoshiki Kubota, Kenichi Kato, Masaki Takata

Research output: Contribution to journalArticle

136 Citations (Scopus)

Abstract

We have investigated the hydrogen absorption/desorption hysteresis by means of in situ powder X-ray diffraction (XRD) and solid-state 2H NMR to clarify the location of hydrogen, surface or body, and its chemical form, molecular, atomic, or as hydride. The present results point out that strongly trapped hydrogen atoms exist inside the Pd nanoparticles due to a strong Pd-H bond formation and are stabilized in the lattice of Pd nanoparticles, compared to bulk Pd.

Original languageEnglish
Pages (from-to)1828-1829
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number6
DOIs
Publication statusPublished - Feb 13 2008

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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