Abstract
The structure of the addition reaction product of 2-benzoxypentafluoropropene [CF2 = C(CF3) OCOC6H5] with 1,4-dioxane was investigated by the crystallographic analysis of the single crystal to conclude that the 2,6-disubstitution of 1,4-dioxane took place, on the contrary to the assumption that the reaction would take place at the 2- and 5-positions based on the product structure of 2-benzoxypentafluoropropene with tetrahydrofuran. Modified polyaddition reaction mechanism of bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2 = C(CF3)OCO-C6 H4-COOC(CF3) = CF2] with 1,4-dioxane including 1,5-radical shift mechanism is proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 1461-1464 |
| Number of pages | 4 |
| Journal | Journal of Fluorine Chemistry |
| Volume | 125 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - Oct 1 2004 |
| Externally published | Yes |
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All Science Journal Classification (ASJC) codes
- Biochemistry
- Environmental Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
Cite this
On the structure of the radical addition product of 2-benzoxypentafluoropropene with 1,4-dioxane. / Fujiwara, Hirotada; Iwasaki, Masakazu; Narita, Tadashi; Hamana, Hiroshi.
In: Journal of Fluorine Chemistry, Vol. 125, No. 10, 01.10.2004, p. 1461-1464.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - On the structure of the radical addition product of 2-benzoxypentafluoropropene with 1,4-dioxane
AU - Fujiwara, Hirotada
AU - Iwasaki, Masakazu
AU - Narita, Tadashi
AU - Hamana, Hiroshi
PY - 2004/10/1
Y1 - 2004/10/1
N2 - The structure of the addition reaction product of 2-benzoxypentafluoropropene [CF2 = C(CF3) OCOC6H5] with 1,4-dioxane was investigated by the crystallographic analysis of the single crystal to conclude that the 2,6-disubstitution of 1,4-dioxane took place, on the contrary to the assumption that the reaction would take place at the 2- and 5-positions based on the product structure of 2-benzoxypentafluoropropene with tetrahydrofuran. Modified polyaddition reaction mechanism of bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2 = C(CF3)OCO-C6 H4-COOC(CF3) = CF2] with 1,4-dioxane including 1,5-radical shift mechanism is proposed.
AB - The structure of the addition reaction product of 2-benzoxypentafluoropropene [CF2 = C(CF3) OCOC6H5] with 1,4-dioxane was investigated by the crystallographic analysis of the single crystal to conclude that the 2,6-disubstitution of 1,4-dioxane took place, on the contrary to the assumption that the reaction would take place at the 2- and 5-positions based on the product structure of 2-benzoxypentafluoropropene with tetrahydrofuran. Modified polyaddition reaction mechanism of bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2 = C(CF3)OCO-C6 H4-COOC(CF3) = CF2] with 1,4-dioxane including 1,5-radical shift mechanism is proposed.
UR - http://www.scopus.com/inward/record.url?scp=4644249119&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=4644249119&partnerID=8YFLogxK
U2 - 10.1016/j.jfluchem.2004.05.005
DO - 10.1016/j.jfluchem.2004.05.005
M3 - Article
AN - SCOPUS:4644249119
VL - 125
SP - 1461
EP - 1464
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
IS - 10
ER -