Abstract
The structure of the addition reaction product of 2-benzoxypentafluoropropene [CF2 = C(CF3) OCOC6H5] with 1,4-dioxane was investigated by the crystallographic analysis of the single crystal to conclude that the 2,6-disubstitution of 1,4-dioxane took place, on the contrary to the assumption that the reaction would take place at the 2- and 5-positions based on the product structure of 2-benzoxypentafluoropropene with tetrahydrofuran. Modified polyaddition reaction mechanism of bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF2 = C(CF3)OCO-C6 H4-COOC(CF3) = CF2] with 1,4-dioxane including 1,5-radical shift mechanism is proposed.
Original language | English |
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Pages (from-to) | 1461-1464 |
Number of pages | 4 |
Journal | Journal of Fluorine Chemistry |
Volume | 125 |
Issue number | 10 |
DOIs | |
Publication status | Published - Oct 1 2004 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Environmental Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry