One dimensional polymeric photonic crystal doped with second-order nonlinear optical chromophore

Azusa Inoue; Shin ichiro Inoue; Shiyoshi Yokoyama; Keisuke Kojima; Kei Yasui; Masaaki Ozawa; Keisuke Odoi

doi:10.1117/12.809268

One dimensional polymeric photonic crystal doped with second-order nonlinear optical chromophore

Azusa Inoue, Shin ichiro Inoue, Shiyoshi Yokoyama, Keisuke Kojima, Kei Yasui, Masaaki Ozawa, Keisuke Odoi

Department of Advanced Device Materials

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Citation (Scopus)

Abstract

Organic nonlinear optical (NLO) materials have attracted much interest for their potential applications over the past two decades mainly because of their faster electronic response and larger optical nonlinearities than the conventional inorganic materials. Especially, electro-optic (EO) polymers have been promising candidates for fast and broadband EO modulators as a result of the development of the 2nd-order NLO chromophore. In this manuscript, we report fabrication and design of one dimensional (1D) polymeric photonic crystals (PCs) to additionally enhance the optical nonlinearities of the organic NLO materials. We fabricated polymeric high-reflection mirrors for 1D PCs by a simple alternatively spin-coating two polymers under control of their optical thickness, in which a novel polymer was applied to the higher refractive index layer. We also designed defect-mode 1D polymeric PC for effective light-localization in the defect layer and discussed their effect for enhancement of the 2nd-order optical nonlinearities.

Original language	English
Title of host publication	Organic Photonic Materials and Devices XI
DOIs	https://doi.org/10.1117/12.809268
Publication status	Published - 2009
Event	Organic Photonic Materials and Devices XI - San Jose, CA, United States Duration: Jan 27 2009 → Jan 29 2009

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	7213
ISSN (Print)	0277-786X

Other

Other	Organic Photonic Materials and Devices XI
Country	United States
City	San Jose, CA
Period	1/27/09 → 1/29/09

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

Access to Document

10.1117/12.809268

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One dimensional polymeric photonic crystal doped with second-order nonlinear optical chromophore. / Inoue, Azusa; Inoue, Shin ichiro; Yokoyama, Shiyoshi; Kojima, Keisuke; Yasui, Kei; Ozawa, Masaaki; Odoi, Keisuke.

Organic Photonic Materials and Devices XI. 2009. 72131C (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 7213).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Inoue, A, Inoue, SI, Yokoyama, S, Kojima, K, Yasui, K, Ozawa, M & Odoi, K 2009, One dimensional polymeric photonic crystal doped with second-order nonlinear optical chromophore. in Organic Photonic Materials and Devices XI., 72131C, Proceedings of SPIE - The International Society for Optical Engineering, vol. 7213, Organic Photonic Materials and Devices XI, San Jose, CA, United States, 1/27/09. https://doi.org/10.1117/12.809268

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AU - Yasui, Kei

AU - Ozawa, Masaaki

AU - Odoi, Keisuke

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AB - Organic nonlinear optical (NLO) materials have attracted much interest for their potential applications over the past two decades mainly because of their faster electronic response and larger optical nonlinearities than the conventional inorganic materials. Especially, electro-optic (EO) polymers have been promising candidates for fast and broadband EO modulators as a result of the development of the 2nd-order NLO chromophore. In this manuscript, we report fabrication and design of one dimensional (1D) polymeric photonic crystals (PCs) to additionally enhance the optical nonlinearities of the organic NLO materials. We fabricated polymeric high-reflection mirrors for 1D PCs by a simple alternatively spin-coating two polymers under control of their optical thickness, in which a novel polymer was applied to the higher refractive index layer. We also designed defect-mode 1D polymeric PC for effective light-localization in the defect layer and discussed their effect for enhancement of the 2nd-order optical nonlinearities.

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