One-electron oxidized nickel(II)-(disalicylidene)diamine complex

Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states

Yuichi Shimazaki, Fumito Tani, Kôichi Fukui, Yoshinori Naruta, Osamu Yamauchi

Research output: Contribution to journalArticle

151 Citations (Scopus)

Abstract

The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at <-120 °C, indicating that the oxidation state is temperature dependent.

Original languageEnglish
Pages (from-to)10512-10513
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number35
DOIs
Publication statusPublished - Sep 3 2003

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Diamines
Nickel
Electrons
Temperature
Oxidation
phenoxy radical

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

One-electron oxidized nickel(II)-(disalicylidene)diamine complex : Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states. / Shimazaki, Yuichi; Tani, Fumito; Fukui, Kôichi; Naruta, Yoshinori; Yamauchi, Osamu.

In: Journal of the American Chemical Society, Vol. 125, No. 35, 03.09.2003, p. 10512-10513.

Research output: Contribution to journalArticle

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abstract = "The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at <-120 °C, indicating that the oxidation state is temperature dependent.",
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AU - Yamauchi, Osamu

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