One-electron oxidized nickel(II)-(disalicylidene)diamine complex: Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states

Yuichi Shimazaki, Fumito Tani, Kôichi Fukui, Yoshinori Naruta, Osamu Yamauchi

Research output: Contribution to journalArticlepeer-review

159 Citations (Scopus)

Abstract

The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at <-120 °C, indicating that the oxidation state is temperature dependent.

Original languageEnglish
Pages (from-to)10512-10513
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number35
DOIs
Publication statusPublished - Sep 3 2003

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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