One-electron oxidized nickel(II)-(disalicylidene)diamine complex: Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states

Yuichi Shimazaki; Fumito Tani; Kôichi Fukui; Yoshinori Naruta; Osamu Yamauchi

doi:10.1021/ja035806o

One-electron oxidized nickel(II)-(disalicylidene)diamine complex: Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states

Yuichi Shimazaki, Fumito Tani, Kôichi Fukui, Yoshinori Naruta, Osamu Yamauchi

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

171 Citations (Scopus)

Abstract

The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at <-120 °C, indicating that the oxidation state is temperature dependent.

Original language	English
Pages (from-to)	10512-10513
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	35
DOIs	https://doi.org/10.1021/ja035806o
Publication status	Published - Sept 3 2003

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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One-electron oxidized nickel(II)-(disalicylidene)diamine complex : Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states. / Shimazaki, Yuichi; Tani, Fumito; Fukui, Kôichi et al.

In: Journal of the American Chemical Society, Vol. 125, No. 35, 03.09.2003, p. 10512-10513.

Research output: Contribution to journal › Article › peer-review

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abstract = "The one-electron oxidized species of a Ni(II)-phenolate complex has been shown to be in the Ni(II)-phenoxyl radical state at room temperature and the Ni(III)-phenolate state at <-120 °C, indicating that the oxidation state is temperature dependent.",

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AU - Naruta, Yoshinori

AU - Yamauchi, Osamu

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One-electron oxidized nickel(II)-(disalicylidene)diamine complex: Temperature-dependent tautomerism between Ni(III)-phenolate and Ni(II)-phenoxyl radical states

Abstract

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