One-pot synthesis of 2,5-diformylfuran from carbohydrate derivatives by sulfonated resin and hydrotalcite-supported ruthenium catalysts

Atsushi Takagaki, Miho Takahashi, Shun Nishimura, Kohki Ebitani

Research output: Contribution to journalArticle

169 Citations (Scopus)

Abstract

2,5-Diformylfuran (DFF) was selectively synthesized from 5-hydroxymethylfurfural using a hydrotalcite-supported ruthenium catalyst (Ru/HT) by oxidation with molecular oxygen under mild reaction conditions. A combination of hydrotalcite, Amberlyst-15, and Ru/HT catalysts successfully afforded direct synthesis of DFF from hexoses such as fructose and glucose via isomerization, dehydration, and successive selective oxidation in one pot. Stepwise addition of catalyst improved DFF yield up to 49% from fructose and 25% from glucose, respectively.

Original languageEnglish
Pages (from-to)1562-1565
Number of pages4
JournalACS Catalysis
Volume1
Issue number11
DOIs
Publication statusPublished - Nov 4 2011
Externally publishedYes

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hydrotalcite
Ruthenium
Carbohydrates
Fructose
Resins
Derivatives
Catalysts
Glucose
Oxidation
Hexoses
Molecular oxygen
Isomerization
Dehydration
2,5-diformylfuran

All Science Journal Classification (ASJC) codes

  • Catalysis

Cite this

One-pot synthesis of 2,5-diformylfuran from carbohydrate derivatives by sulfonated resin and hydrotalcite-supported ruthenium catalysts. / Takagaki, Atsushi; Takahashi, Miho; Nishimura, Shun; Ebitani, Kohki.

In: ACS Catalysis, Vol. 1, No. 11, 04.11.2011, p. 1562-1565.

Research output: Contribution to journalArticle

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