One-step synthesis of hyper-branched polymer with perfluoroalkyl segments

Masayuki Haraguchi, Tomoyasu Hirai, Masahiro Ozawa, Misao Miyamoto, Keiji Tanaka

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Initiator-fragment incorporation radical polymerization (IFIRP) of commercially available fluorinated monomers was performed in the presence of cross-linking agents, resulting in a hyperbranched polymer with perfluoroalkyl groups (F-HBP). In our one-step method, a F-HBP was successfully prepared without gelation within 1 h. The FHBP exhibited interesting properties based on both the hyperbranched architecture and the perfluoroalkyl groups, such as good solubility in common organic solvents, high thermal stability, and low surface free energy.

Original languageEnglish
Pages (from-to)34-38
Number of pages5
JournalKGK Kautschuk Gummi Kunststoffe
Volume65
Issue number7-8
Publication statusPublished - Jul 1 2012

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Gelation
Free radical polymerization
Organic solvents
Free energy
Polymers
Thermodynamic stability
Solubility
Monomers

All Science Journal Classification (ASJC) codes

  • Mechanical Engineering
  • Polymers and Plastics
  • Industrial and Manufacturing Engineering
  • Materials Chemistry

Cite this

One-step synthesis of hyper-branched polymer with perfluoroalkyl segments. / Haraguchi, Masayuki; Hirai, Tomoyasu; Ozawa, Masahiro; Miyamoto, Misao; Tanaka, Keiji.

In: KGK Kautschuk Gummi Kunststoffe, Vol. 65, No. 7-8, 01.07.2012, p. 34-38.

Research output: Contribution to journalArticle

Haraguchi, M, Hirai, T, Ozawa, M, Miyamoto, M & Tanaka, K 2012, 'One-step synthesis of hyper-branched polymer with perfluoroalkyl segments', KGK Kautschuk Gummi Kunststoffe, vol. 65, no. 7-8, pp. 34-38.
Haraguchi, Masayuki ; Hirai, Tomoyasu ; Ozawa, Masahiro ; Miyamoto, Misao ; Tanaka, Keiji. / One-step synthesis of hyper-branched polymer with perfluoroalkyl segments. In: KGK Kautschuk Gummi Kunststoffe. 2012 ; Vol. 65, No. 7-8. pp. 34-38.
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