Optimized conjugative bridge and its length in novel chromophores for electro-optical applications

Xianmin M. Zhang, Han Bao, Gaowu W. Qin, Shiyoshi Yokoyama

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Two group chromophores with strong methoxy electron donor and CF3 electron acceptor were synthesized and reported. To investigate the effects of conjugative bond and its length between electron donor and acceptor on optical properties, thiophene ring was incorporated into the conjugated units of group B compared to group A. The results showed that the incorporation of thiophene rings could significantly enhance molecular first hyperpolarizability and permit a high thermal stability. It has been found that molecular first hyperpolarizability increased continually by the increase of bond length of group A. However, further increase of conjugated bond length between electron donor and acceptor in group B reduced the molecular hyperpolarizability. This study indicates that both the nature of the conjugative bridge and its bond length between electron donor and acceptor have inner correlation to optimize the molecular hyperpolarizability for electro-optical applications.

Original languageEnglish
Title of host publicationMaterials and Technologies for Energy Supply and Environmental Engineering
EditorsGuangxian Li, Fusheng Pan, Fusheng Pan, Yafang Han, Ying Wu, Runhua Fan, Xuefeng Liu, Fusheng Pan
PublisherTrans Tech Publications Ltd
Pages117-122
Number of pages6
ISBN (Print)9783038356561
DOIs
Publication statusPublished - Jan 1 2016
EventChinese Materials Conference on Materials and Technologies for Energy Supply and Environmental Engineering, 2015 - Guiyang, China
Duration: Jul 10 2015Jul 14 2015

Publication series

NameMaterials Science Forum
Volume847
ISSN (Print)0255-5476

Other

OtherChinese Materials Conference on Materials and Technologies for Energy Supply and Environmental Engineering, 2015
CountryChina
CityGuiyang
Period7/10/157/14/15

Fingerprint

Chromophores
chromophores
Bond length
Electrons
Thiophenes
Thiophene
thiophenes
electrons
rings
Thermodynamic stability
thermal stability
Optical properties
optical properties

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Zhang, X. M., Bao, H., Qin, G. W., & Yokoyama, S. (2016). Optimized conjugative bridge and its length in novel chromophores for electro-optical applications. In G. Li, F. Pan, F. Pan, Y. Han, Y. Wu, R. Fan, X. Liu, ... F. Pan (Eds.), Materials and Technologies for Energy Supply and Environmental Engineering (pp. 117-122). (Materials Science Forum; Vol. 847). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/MSF.847.117

Optimized conjugative bridge and its length in novel chromophores for electro-optical applications. / Zhang, Xianmin M.; Bao, Han; Qin, Gaowu W.; Yokoyama, Shiyoshi.

Materials and Technologies for Energy Supply and Environmental Engineering. ed. / Guangxian Li; Fusheng Pan; Fusheng Pan; Yafang Han; Ying Wu; Runhua Fan; Xuefeng Liu; Fusheng Pan. Trans Tech Publications Ltd, 2016. p. 117-122 (Materials Science Forum; Vol. 847).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Zhang, XM, Bao, H, Qin, GW & Yokoyama, S 2016, Optimized conjugative bridge and its length in novel chromophores for electro-optical applications. in G Li, F Pan, F Pan, Y Han, Y Wu, R Fan, X Liu & F Pan (eds), Materials and Technologies for Energy Supply and Environmental Engineering. Materials Science Forum, vol. 847, Trans Tech Publications Ltd, pp. 117-122, Chinese Materials Conference on Materials and Technologies for Energy Supply and Environmental Engineering, 2015, Guiyang, China, 7/10/15. https://doi.org/10.4028/www.scientific.net/MSF.847.117
Zhang XM, Bao H, Qin GW, Yokoyama S. Optimized conjugative bridge and its length in novel chromophores for electro-optical applications. In Li G, Pan F, Pan F, Han Y, Wu Y, Fan R, Liu X, Pan F, editors, Materials and Technologies for Energy Supply and Environmental Engineering. Trans Tech Publications Ltd. 2016. p. 117-122. (Materials Science Forum). https://doi.org/10.4028/www.scientific.net/MSF.847.117
Zhang, Xianmin M. ; Bao, Han ; Qin, Gaowu W. ; Yokoyama, Shiyoshi. / Optimized conjugative bridge and its length in novel chromophores for electro-optical applications. Materials and Technologies for Energy Supply and Environmental Engineering. editor / Guangxian Li ; Fusheng Pan ; Fusheng Pan ; Yafang Han ; Ying Wu ; Runhua Fan ; Xuefeng Liu ; Fusheng Pan. Trans Tech Publications Ltd, 2016. pp. 117-122 (Materials Science Forum).
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