Order-disorder transition of symmetric poly(styrene-b-2-vinylpyridine) in bulk and solution

Yoshiaki Takahashi, Shinichi Kitade, Masahiro Noda, Nobuo Ochiai, Ichiro Noda, Masayuki Imai, Yushu Matsushita

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Order-disorder transitions (ODT) of symmetric poly(styrene-b-2-vinylpyridine) in a common good solvent and bulk were determined by dynamic rheological and small-angle neutron scattering measurements. ODT conditions determined by both methods are consistent with each other and the degree of polymerization dependence of critical volume fraction in solution at almost constant temperature agrees with the theoretical prediction for semidilute solutions. However, semidilute behavior persists to a much higher concentration than for ordinary polymer solutions and the crossover from semidilute to concentrated regimes is not clear.

Original languageEnglish
Pages (from-to)388-393
Number of pages6
JournalPolymer Journal
Volume30
Issue number5
DOIs
Publication statusPublished - Jan 1 1998
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

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