TY - JOUR
T1 - Ordered carbonaceous frameworks
T2 - a new class of carbon materials with molecular-level design
AU - Yoshii, Takeharu
AU - Chida, Koki
AU - Nishihara, Hirotomo
AU - Tani, Fumito
N1 - Funding Information:
This work was supported by JST CREST Grant no. JPMJCRI18R3; JSPS KAKENHI Grant no. 21K14490; the ‘‘Five-star Alliance’’ in ‘‘NJRC Mater. & Dev.’’; Japan Association for Chemical Innovation; JST SICORP Grant no. JPMJSC2112. The authors thank Prof. T. Ogoshi, Prof. K. Kamiya, Prof. R. Sakamoto, and Prof. Y. Nishina for the development of the relevant field and precious discussions. The authors also thank Dr T. Kamimura, Dr M. Inoue, Dr H. Nobukuni, Ms M. Ohwada, Mr T. Hirota, and all the previous co-authors of the relevant work for their considerable support and experimental contributions.
Publisher Copyright:
© 2022 The Royal Society of Chemistry
PY - 2022/2/15
Y1 - 2022/2/15
N2 - Ordered carbonaceous frameworks (OCFs) are a new class of carbon materials with a three-dimensional ordered structure synthesized by simple carbonization of metalloporphyrin crystals with polymerizable moieties. Carbonization via solid-state polymerization results in the formation of graphene-based ordered frameworks in which regularly aligned single-atomic metals are embedded. These unique structural features afford molecular-level designability like organic-based frameworks together with high electrical conductivity, thermal/chemical stability, and mechanical flexibility, towards a variety of applications including electrocatalysis and force-driven phase transition. This feature article summarizes the synthetic strategies and characteristics of OCFs in comparison with conventional organic-based frameworks and porous carbons, to discuss the potential applications and further development of the OCF family.
AB - Ordered carbonaceous frameworks (OCFs) are a new class of carbon materials with a three-dimensional ordered structure synthesized by simple carbonization of metalloporphyrin crystals with polymerizable moieties. Carbonization via solid-state polymerization results in the formation of graphene-based ordered frameworks in which regularly aligned single-atomic metals are embedded. These unique structural features afford molecular-level designability like organic-based frameworks together with high electrical conductivity, thermal/chemical stability, and mechanical flexibility, towards a variety of applications including electrocatalysis and force-driven phase transition. This feature article summarizes the synthetic strategies and characteristics of OCFs in comparison with conventional organic-based frameworks and porous carbons, to discuss the potential applications and further development of the OCF family.
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U2 - 10.1039/d1cc07228e
DO - 10.1039/d1cc07228e
M3 - Article
C2 - 35254359
AN - SCOPUS:85126830223
VL - 58
SP - 3578
EP - 3590
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 22
ER -