Ordinary and Hot Electroluminescence from Single-Molecule Devices: Controlling the Emission Color by Chemical Engineering

Michael C. Chong, Lydia Sosa-Vargas, Hervé Bulou, Alex Boeglin, Fabrice Scheurer, Fabrice Mathevet, Guillaume Schull

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Single-molecule junctions specifically designed for their optical properties are operated as light-emitting devices using a cryogenic scanning tunneling microscope. They are composed of an emitting unit - a molecular chromophore - suspended between a Au(111) surface and the tip of the microscope by organic linkers. Tunneling electrons flowing through these junctions generate a narrow-line emission of light whose color is controlled by carefully selecting the chemical structure of the emitting unit. Besides the main emission line, red and blue-shifted vibronic features of low intensity are also detected. While the red-shifted features provide a spectroscopic fingerprint of the emitting unit, the blue-shifted ones are interpreted in terms of hot luminescence from vibrationally excited states of the molecule.

Original languageEnglish
Pages (from-to)6480-6484
Number of pages5
JournalNano Letters
Volume16
Issue number10
DOIs
Publication statusPublished - Oct 12 2016

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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    Chong, M. C., Sosa-Vargas, L., Bulou, H., Boeglin, A., Scheurer, F., Mathevet, F., & Schull, G. (2016). Ordinary and Hot Electroluminescence from Single-Molecule Devices: Controlling the Emission Color by Chemical Engineering. Nano Letters, 16(10), 6480-6484. https://doi.org/10.1021/acs.nanolett.6b02997