Organic synthesis in solid media. Silica gel as an effective and reusable medium for the selective allylation of aldehydes with tetraallyltin

Yong Zhi Jin, Noriyuki Yasuda, Hiroshi Furuno, Junji Inanaga

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Wet silica gel promotes the chemoselective and almost complete allylation of aldehydes with 0.25-0.30 molar equivalents of tetraallyltin without an organic solvent, leaving no organotin compounds, requiring neither extraction nor chromatographic separation after the reaction, and enabling the repeated use of the silica gel.

Original languageEnglish
Pages (from-to)8765-8768
Number of pages4
JournalTetrahedron Letters
Volume44
Issue number49
DOIs
Publication statusPublished - Dec 1 2003

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this