Organic synthesis in solid media. Silica gel as an effective and reusable medium for the selective allylation of aldehydes with tetraallyltin

Yong Zhi Jin, Noriyuki Yasuda, Hiroshi Furuno, Junji Inanaga

    Research output: Contribution to journalArticlepeer-review

    25 Citations (Scopus)

    Abstract

    Wet silica gel promotes the chemoselective and almost complete allylation of aldehydes with 0.25-0.30 molar equivalents of tetraallyltin without an organic solvent, leaving no organotin compounds, requiring neither extraction nor chromatographic separation after the reaction, and enabling the repeated use of the silica gel.

    Original languageEnglish
    Pages (from-to)8765-8768
    Number of pages4
    JournalTetrahedron Letters
    Volume44
    Issue number49
    DOIs
    Publication statusPublished - Dec 1 2003

    All Science Journal Classification (ASJC) codes

    • Biochemistry
    • Drug Discovery
    • Organic Chemistry

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