Organometallic Catalysts for Use in a Fuel Cell

Takahiro Matsumoto; Kyoungmok Kim; Hidetaka Nakai; Takashi Hibino; Seiji Ogo

doi:10.1002/cctc.201200595

Organometallic Catalysts for Use in a Fuel Cell

Takahiro Matsumoto, Kyoungmok Kim, Hidetaka Nakai, Takashi Hibino, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

We report the successful increase in performance of a fuel cell based on organometallic catalysis. An organometallic [Ni^IIRu^IV] peroxo complex functions as cathode catalyst and was designed following mechanistic consideration of the cell. It was confirmed that the organometallic [Ni^IIRu^IV] peroxo catalyst could function in the fuel cell with a 240% increase in power output over our previous systems. This organometallic catalyst can act in both solid and solution phases and allows observation of the mechanism, hence providing us further opportunity for future improvement.

Original language	English
Pages (from-to)	1368-1373
Number of pages	6
Journal	ChemCatChem
Volume	5
Issue number	6
DOIs	https://doi.org/10.1002/cctc.201200595
Publication status	Published - Jun 2013

All Science Journal Classification (ASJC) codes

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "We report the successful increase in performance of a fuel cell based on organometallic catalysis. An organometallic [NiIIRuIV] peroxo complex functions as cathode catalyst and was designed following mechanistic consideration of the cell. It was confirmed that the organometallic [NiIIRuIV] peroxo catalyst could function in the fuel cell with a 240% increase in power output over our previous systems. This organometallic catalyst can act in both solid and solution phases and allows observation of the mechanism, hence providing us further opportunity for future improvement.",

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AU - Nakai, Hidetaka

AU - Hibino, Takashi

AU - Ogo, Seiji

PY - 2013/6

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AB - We report the successful increase in performance of a fuel cell based on organometallic catalysis. An organometallic [NiIIRuIV] peroxo complex functions as cathode catalyst and was designed following mechanistic consideration of the cell. It was confirmed that the organometallic [NiIIRuIV] peroxo catalyst could function in the fuel cell with a 240% increase in power output over our previous systems. This organometallic catalyst can act in both solid and solution phases and allows observation of the mechanism, hence providing us further opportunity for future improvement.

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Organometallic Catalysts for Use in a Fuel Cell

Abstract

All Science Journal Classification (ASJC) codes

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