Organopalladium and platinum complexes of C60 bearing isonitrile ligands

Hideo Nagashima; Mitsuhiko Nakazawa; Takeshi Furukawa; Kenji Itoh

doi:10.1246/cl.1996.405

Organopalladium and platinum complexes of C₆₀ bearing isonitrile ligands

Hideo Nagashima, Mitsuhiko Nakazawa, Takeshi Furukawa, Kenji Itoh

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Organopalladium or platinum complexes, (η²-C₆₀)M(CNR)₂ (1 M =Pt, 3; M - Pd: R = ^tBu, 2,6-Me₂C₆H₃, 2,4,6-Me₃C₆H₂, cyclohexyl) were synthesized from C₆₀M_n (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η²-C₆₀)Pt(CNR)₄ (2) in the case where R = 2,6-Me₂C₆H₃, 2,4,6-Me₃C₆H₂, cyclohexyl).

Original language	English
Pages (from-to)	405-406
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.1996.405
Publication status	Published - 1996

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1996.405

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@article{d71bf5eb7e6d413fb0104ffe523560d3,

title = "Organopalladium and platinum complexes of C60 bearing isonitrile ligands",

abstract = "Organopalladium or platinum complexes, (η2-C60)M(CNR)2 (1 M =Pt, 3; M - Pd: R = tBu, 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl) were synthesized from C60Mn (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η2-C60)Pt(CNR)4 (2) in the case where R = 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl).",

author = "Hideo Nagashima and Mitsuhiko Nakazawa and Takeshi Furukawa and Kenji Itoh",

year = "1996",

doi = "10.1246/cl.1996.405",

language = "English",

pages = "405--406",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "5",

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TY - JOUR

T1 - Organopalladium and platinum complexes of C60 bearing isonitrile ligands

AU - Nagashima, Hideo

AU - Nakazawa, Mitsuhiko

AU - Furukawa, Takeshi

AU - Itoh, Kenji

PY - 1996

Y1 - 1996

N2 - Organopalladium or platinum complexes, (η2-C60)M(CNR)2 (1 M =Pt, 3; M - Pd: R = tBu, 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl) were synthesized from C60Mn (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η2-C60)Pt(CNR)4 (2) in the case where R = 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl).

AB - Organopalladium or platinum complexes, (η2-C60)M(CNR)2 (1 M =Pt, 3; M - Pd: R = tBu, 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl) were synthesized from C60Mn (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η2-C60)Pt(CNR)4 (2) in the case where R = 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl).

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U2 - 10.1246/cl.1996.405

DO - 10.1246/cl.1996.405

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JF - Chemistry Letters

SN - 0366-7022

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