TY - JOUR
T1 - Organopalladium and platinum complexes of C60 bearing isonitrile ligands
AU - Nagashima, Hideo
AU - Nakazawa, Mitsuhiko
AU - Furukawa, Takeshi
AU - Itoh, Kenji
PY - 1996
Y1 - 1996
N2 - Organopalladium or platinum complexes, (η2-C60)M(CNR)2 (1 M =Pt, 3; M - Pd: R = tBu, 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl) were synthesized from C60Mn (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η2-C60)Pt(CNR)4 (2) in the case where R = 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl).
AB - Organopalladium or platinum complexes, (η2-C60)M(CNR)2 (1 M =Pt, 3; M - Pd: R = tBu, 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl) were synthesized from C60Mn (M = Pd, Pt; n = ca. 1) and the corresponding isonitriles. Unprecedented reaction of 1 with additional isonitriles occurred to form (η2-C60)Pt(CNR)4 (2) in the case where R = 2,6-Me2C6H3, 2,4,6-Me3C6H2, cyclohexyl).
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U2 - 10.1246/cl.1996.405
DO - 10.1246/cl.1996.405
M3 - Article
AN - SCOPUS:0030514803
SP - 405
EP - 406
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 5
ER -