TY - JOUR
T1 - Oxidation reactivity of bis(m-oxo) dinickel(iii) complexes
T2 - Arene hydroxylation of the supporting ligand
AU - Honda, Kaoru
AU - Cho, Jaeheung
AU - Matsumoto, Takahiro
AU - Roh, Jungyun
AU - Furutachi, Hideki
AU - Tosha, Takehiko
AU - Kubo, Minoru
AU - Fujinami, Shuhei
AU - Ogura, Takashi
AU - Kitagawa, Teizo
AU - Suzuki, Masatatsu
PY - 2009/4/20
Y1 - 2009/4/20
N2 - In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H2O2, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. Kinetic studies reveal that hydroxylation proceeds by electrophilic aromatic substitution. The lower reactivity than the corresponding μ - η2: η2 - peroxo dicopper(II) complexes can be attributed to unfavorable entropy effects.
AB - In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H2O2, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. Kinetic studies reveal that hydroxylation proceeds by electrophilic aromatic substitution. The lower reactivity than the corresponding μ - η2: η2 - peroxo dicopper(II) complexes can be attributed to unfavorable entropy effects.
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U2 - 10.1002/anie.200900222
DO - 10.1002/anie.200900222
M3 - Article
C2 - 19347913
AN - SCOPUS:70349778995
SN - 1433-7851
VL - 48
SP - 3304
EP - 3307
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 18
ER -