Oxidation reactivity of bis(m-oxo) dinickel(iii) complexes: Arene hydroxylation of the supporting ligand

Kaoru Honda, Jaeheung Cho, Takahiro Matsumoto, Jungyun Roh, Hideki Furutachi, Takehiko Tosha, Minoru Kubo, Shuhei Fujinami, Takashi Ogura, Teizo Kitagawa, Masatatsu Suzuki

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

In the nick(el) of time: Bis(μ-oxo) dinickel(III) complexes 2 (see scheme), generated in the reaction of 1 with H2O2, are capable of hydroxylating the xylyl linker of the supporting ligand to give 3. Kinetic studies reveal that hydroxylation proceeds by electrophilic aromatic substitution. The lower reactivity than the corresponding μ - η2: η2 - peroxo dicopper(II) complexes can be attributed to unfavorable entropy effects.

Original languageEnglish
Pages (from-to)3304-3307
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number18
DOIs
Publication statusPublished - Apr 20 2009
Externally publishedYes

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Hydroxylation
Substitution reactions
Entropy
Ligands
Oxidation
Kinetics

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Oxidation reactivity of bis(m-oxo) dinickel(iii) complexes : Arene hydroxylation of the supporting ligand. / Honda, Kaoru; Cho, Jaeheung; Matsumoto, Takahiro; Roh, Jungyun; Furutachi, Hideki; Tosha, Takehiko; Kubo, Minoru; Fujinami, Shuhei; Ogura, Takashi; Kitagawa, Teizo; Suzuki, Masatatsu.

In: Angewandte Chemie - International Edition, Vol. 48, No. 18, 20.04.2009, p. 3304-3307.

Research output: Contribution to journalArticle

Honda, K, Cho, J, Matsumoto, T, Roh, J, Furutachi, H, Tosha, T, Kubo, M, Fujinami, S, Ogura, T, Kitagawa, T & Suzuki, M 2009, 'Oxidation reactivity of bis(m-oxo) dinickel(iii) complexes: Arene hydroxylation of the supporting ligand', Angewandte Chemie - International Edition, vol. 48, no. 18, pp. 3304-3307. https://doi.org/10.1002/anie.200900222
Honda, Kaoru ; Cho, Jaeheung ; Matsumoto, Takahiro ; Roh, Jungyun ; Furutachi, Hideki ; Tosha, Takehiko ; Kubo, Minoru ; Fujinami, Shuhei ; Ogura, Takashi ; Kitagawa, Teizo ; Suzuki, Masatatsu. / Oxidation reactivity of bis(m-oxo) dinickel(iii) complexes : Arene hydroxylation of the supporting ligand. In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 18. pp. 3304-3307.
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