Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer

Gloria Agusti; Ryo Ohtani; Ko Yoneda; Ana B. Gaspar; Masaaki Ohba; Juan F. Sánchez-Royo; M. Carmen Muñoz; Susumu Kitagawa; José A. Real

doi:10.1002/anie.200904379

Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer

Gloria Agusti, Ryo Ohtani, Ko Yoneda, Ana B. Gaspar, Masaaki Ohba, Juan F. Sánchez-Royo, M. Carmen Muñoz, Susumu Kitagawa, José A. Real

Research output: Contribution to journal › Article

128 Citations (Scopus)

Abstract

Mixing with the guests: Exposure of the porous spin-crossover framework {Fe(pz)[Ptll(CN)4]}to X2(pz=pyrazine; X2=Cl2, Br2, and 12) leads to incorporation of the halides in the coordi natively unsaturated [Ptll(CN)4]2- moieties through oxidative addition, thus affording the mixed-valence series {Fe(pz)[Ptll/IV(CN)4(X)]], which features quite distinct cooperative spin-transition properties.

Original language	English
Pages (from-to)	8944-8947
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	47
DOIs	https://doi.org/10.1002/anie.200904379
Publication status	Published - Nov 9 2009
Externally published	Yes

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All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Cite this

Agusti, G., Ohtani, R., Yoneda, K., Gaspar, A. B., Ohba, M., Sánchez-Royo, J. F., ... Real, J. A. (2009). Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer. Angewandte Chemie - International Edition, 48(47), 8944-8947. https://doi.org/10.1002/anie.200904379

Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer. / Agusti, Gloria; Ohtani, Ryo; Yoneda, Ko; Gaspar, Ana B.; Ohba, Masaaki; Sánchez-Royo, Juan F.; Carmen Muñoz, M.; Kitagawa, Susumu; Real, José A.

In: Angewandte Chemie - International Edition, Vol. 48, No. 47, 09.11.2009, p. 8944-8947.

Research output: Contribution to journal › Article

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Access to Document

10.1002/anie.200904379