TY - JOUR
T1 - Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer
AU - Agusti, Gloria
AU - Ohtani, Ryo
AU - Yoneda, Ko
AU - Gaspar, Ana B.
AU - Ohba, Masaaki
AU - Sánchez-Royo, Juan F.
AU - Carmen Muñoz, M.
AU - Kitagawa, Susumu
AU - Real, José A.
PY - 2009/11/9
Y1 - 2009/11/9
N2 - Mixing with the guests: Exposure of the porous spin-crossover framework {Fe(pz)[Ptll(CN)4]}to X2(pz=pyrazine; X2=Cl2, Br2, and 12) leads to incorporation of the halides in the coordi natively unsaturated [Ptll(CN)4]2- moieties through oxidative addition, thus affording the mixed-valence series {Fe(pz)[Ptll/IV(CN)4(X)]], which features quite distinct cooperative spin-transition properties.
AB - Mixing with the guests: Exposure of the porous spin-crossover framework {Fe(pz)[Ptll(CN)4]}to X2(pz=pyrazine; X2=Cl2, Br2, and 12) leads to incorporation of the halides in the coordi natively unsaturated [Ptll(CN)4]2- moieties through oxidative addition, thus affording the mixed-valence series {Fe(pz)[Ptll/IV(CN)4(X)]], which features quite distinct cooperative spin-transition properties.
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U2 - 10.1002/anie.200904379
DO - 10.1002/anie.200904379
M3 - Article
C2 - 19856361
AN - SCOPUS:70449116068
VL - 48
SP - 8944
EP - 8947
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 47
ER -