Oxidative addition of halogens on open metal sites in a microporous spin-crossover coordination polymer

Gloria Agusti, Ryo Ohtani, Ko Yoneda, Ana B. Gaspar, Masaaki Ohba, Juan F. Sánchez-Royo, M. Carmen Muñoz, Susumu Kitagawa, José A. Real

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128 Citations (Scopus)

Abstract

Mixing with the guests: Exposure of the porous spin-crossover framework {Fe(pz)[Ptll(CN)4]}to X2(pz=pyrazine; X2=Cl2, Br2, and 12) leads to incorporation of the halides in the coordi natively unsaturated [Ptll(CN)4]2- moieties through oxidative addition, thus affording the mixed-valence series {Fe(pz)[Ptll/IV(CN)4(X)]], which features quite distinct cooperative spin-transition properties.

Original languageEnglish
Pages (from-to)8944-8947
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number47
DOIs
Publication statusPublished - Nov 9 2009
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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