Oxidative cleavage of C{single bond}C bond of 2-phenylpropionaldehyde using molecular oxygen

Makoto Tokunaga, Hiroshi Aoyama, Yuki Shirogane, Yasushi Obora, Yasushi Tsuji

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Oxidative C{single bond}C bond cleavage between carbonyl carbon and vicinal carbon of 2-phenylpropionaldehyde to give acetophenone using 1 atm molecular oxygen as oxidant was catalyzed by Ce(IV), V(IV) and Brønsted acids. Among the examined catalysts, sulfuric acid exhibited the highest activity and gave the product in 99% yield.

Original languageEnglish
Pages (from-to)138-140
Number of pages3
JournalCatalysis Today
Volume117
Issue number1-3
DOIs
Publication statusPublished - Sep 30 2006
Externally publishedYes

Fingerprint

Molecular oxygen
Carbon
Oxidants
Sulfuric acid
Catalysts
Acids
single bond
sulfuric acid
acetophenone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Oxidative cleavage of C{single bond}C bond of 2-phenylpropionaldehyde using molecular oxygen. / Tokunaga, Makoto; Aoyama, Hiroshi; Shirogane, Yuki; Obora, Yasushi; Tsuji, Yasushi.

In: Catalysis Today, Vol. 117, No. 1-3, 30.09.2006, p. 138-140.

Research output: Contribution to journalArticle

Tokunaga, Makoto ; Aoyama, Hiroshi ; Shirogane, Yuki ; Obora, Yasushi ; Tsuji, Yasushi. / Oxidative cleavage of C{single bond}C bond of 2-phenylpropionaldehyde using molecular oxygen. In: Catalysis Today. 2006 ; Vol. 117, No. 1-3. pp. 138-140.
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