Oxidative dehydrogenation of ethane using ball-milled hexagonal boron nitride

Yusuke Honda; Atsushi Takagaki; Ryuji Kikuchi; S. Ted Oyama

doi:10.1246/cl.180510

Oxidative dehydrogenation of ethane using ball-milled hexagonal boron nitride

Yusuke Honda, Atsushi Takagaki, Ryuji Kikuchi, S. Ted Oyama

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Ball-milled hexagonal boron nitride (h-BN) involving oxidized boron on the surface was found to catalyze oxidative dehydrogenation of ethane with high selectivity to ethylene (9296%) whereas pristine h-BN showed poor selectivity (42%). The calcination of the ball-milled h-BN at the temperature of 550 °C or higher resulted in the formation of boron oxide on the surface leading to decrease of the activity for the reaction.

Original language	English
Pages (from-to)	1090-1093
Number of pages	4
Journal	Chemistry Letters
Volume	47
Issue number	9
DOIs	https://doi.org/10.1246/cl.180510
Publication status	Published - 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.180510

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title = "Oxidative dehydrogenation of ethane using ball-milled hexagonal boron nitride",

abstract = "Ball-milled hexagonal boron nitride (h-BN) involving oxidized boron on the surface was found to catalyze oxidative dehydrogenation of ethane with high selectivity to ethylene (9296%) whereas pristine h-BN showed poor selectivity (42%). The calcination of the ball-milled h-BN at the temperature of 550 °C or higher resulted in the formation of boron oxide on the surface leading to decrease of the activity for the reaction.",

author = "Yusuke Honda and Atsushi Takagaki and Ryuji Kikuchi and Oyama, {S. Ted}",

note = "Funding Information: This work was supported by a Grant-in-Aid for Challenging Exploratory Research (No. 16K14474) of JSPS, Japan.",

year = "2018",

doi = "10.1246/cl.180510",

language = "English",

volume = "47",

pages = "1090--1093",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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T1 - Oxidative dehydrogenation of ethane using ball-milled hexagonal boron nitride

AU - Honda, Yusuke

AU - Takagaki, Atsushi

AU - Kikuchi, Ryuji

AU - Oyama, S. Ted

N1 - Funding Information: This work was supported by a Grant-in-Aid for Challenging Exploratory Research (No. 16K14474) of JSPS, Japan.

PY - 2018

Y1 - 2018

N2 - Ball-milled hexagonal boron nitride (h-BN) involving oxidized boron on the surface was found to catalyze oxidative dehydrogenation of ethane with high selectivity to ethylene (9296%) whereas pristine h-BN showed poor selectivity (42%). The calcination of the ball-milled h-BN at the temperature of 550 °C or higher resulted in the formation of boron oxide on the surface leading to decrease of the activity for the reaction.

AB - Ball-milled hexagonal boron nitride (h-BN) involving oxidized boron on the surface was found to catalyze oxidative dehydrogenation of ethane with high selectivity to ethylene (9296%) whereas pristine h-BN showed poor selectivity (42%). The calcination of the ball-milled h-BN at the temperature of 550 °C or higher resulted in the formation of boron oxide on the surface leading to decrease of the activity for the reaction.

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U2 - 10.1246/cl.180510

DO - 10.1246/cl.180510

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 9

ER -

Oxidative dehydrogenation of ethane using ball-milled hexagonal boron nitride

Abstract

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