Oxide ion conductivity in doped Ga based perovskite type oxide

Tatsumi Ishihara; Hideaki Matsuda; Mohamad Azmi Bin Bustam; Yusaku Takita

doi:10.1016/0167-2738(96)00122-1

Oxide ion conductivity in doped Ga based perovskite type oxide

Tatsumi Ishihara, Hideaki Matsuda, Mohamad Azmi Bin Bustam, Yusaku Takita

Research output: Contribution to journal › Article › peer-review

96 Citations (Scopus)

Abstract

Oxide ion conductivity of Ga based perovskite type oxides, LnGaO₃ (Ln = Nd, La) and its related oxide, A₃Ga₂O₆ (A = Ba and St) was investigated. Oxide ion transference number is almost 1.0 on Sr₃Ga₂O₆ or Ba₃Ga₂O₆. However, electrical conductivity of these A₃Ga₂O₆ system oxides was lower than log (σ/S cm^-1) = - 3 due to the low solubility of the aliovalent cations. On the other hand, doped perovskite type oxide of NdGaO₃ and LaGaO₃ exhibited a high electrical conductivity and the transference number of oxide ion was higher than 0.9 in the oxygen partial pressure range from PO₂ = 1 to 10^-21 atm. In particular, Ca and Mg doped NdGaO₃ exhibited a high oxide ion conductivity in similar with LaGaO₃ based oxide.

Original language	English
Pages (from-to)	197-201
Number of pages	5
Journal	Solid State Ionics
Volume	86-88
Issue number	PART 1
DOIs	https://doi.org/10.1016/0167-2738(96)00122-1
Publication status	Published - Jul 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1016/0167-2738(96)00122-1

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@article{890d2169f9bc419d86c9ef021b1d4b7a,

title = "Oxide ion conductivity in doped Ga based perovskite type oxide",

abstract = "Oxide ion conductivity of Ga based perovskite type oxides, LnGaO3 (Ln = Nd, La) and its related oxide, A3Ga2O6 (A = Ba and St) was investigated. Oxide ion transference number is almost 1.0 on Sr3Ga2O6 or Ba3Ga2O6. However, electrical conductivity of these A3Ga2O6 system oxides was lower than log (σ/S cm-1) = - 3 due to the low solubility of the aliovalent cations. On the other hand, doped perovskite type oxide of NdGaO3 and LaGaO3 exhibited a high electrical conductivity and the transference number of oxide ion was higher than 0.9 in the oxygen partial pressure range from PO2 = 1 to 10-21 atm. In particular, Ca and Mg doped NdGaO3 exhibited a high oxide ion conductivity in similar with LaGaO3 based oxide.",

author = "Tatsumi Ishihara and Hideaki Matsuda and Bustam, {Mohamad Azmi Bin} and Yusaku Takita",

note = "Funding Information: A part of this work has been carried out as a research project of The Japan Petroleum Institute commissioned by the Petroleum Energy Center with the subsidy of the Ministry of International Trade and Industry.",

year = "1996",

month = jul,

doi = "10.1016/0167-2738(96)00122-1",

language = "English",

volume = "86-88",

pages = "197--201",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier",

number = "PART 1",

}

TY - JOUR

T1 - Oxide ion conductivity in doped Ga based perovskite type oxide

AU - Ishihara, Tatsumi

AU - Matsuda, Hideaki

AU - Bustam, Mohamad Azmi Bin

AU - Takita, Yusaku

N1 - Funding Information: A part of this work has been carried out as a research project of The Japan Petroleum Institute commissioned by the Petroleum Energy Center with the subsidy of the Ministry of International Trade and Industry.

PY - 1996/7

Y1 - 1996/7

N2 - Oxide ion conductivity of Ga based perovskite type oxides, LnGaO3 (Ln = Nd, La) and its related oxide, A3Ga2O6 (A = Ba and St) was investigated. Oxide ion transference number is almost 1.0 on Sr3Ga2O6 or Ba3Ga2O6. However, electrical conductivity of these A3Ga2O6 system oxides was lower than log (σ/S cm-1) = - 3 due to the low solubility of the aliovalent cations. On the other hand, doped perovskite type oxide of NdGaO3 and LaGaO3 exhibited a high electrical conductivity and the transference number of oxide ion was higher than 0.9 in the oxygen partial pressure range from PO2 = 1 to 10-21 atm. In particular, Ca and Mg doped NdGaO3 exhibited a high oxide ion conductivity in similar with LaGaO3 based oxide.

AB - Oxide ion conductivity of Ga based perovskite type oxides, LnGaO3 (Ln = Nd, La) and its related oxide, A3Ga2O6 (A = Ba and St) was investigated. Oxide ion transference number is almost 1.0 on Sr3Ga2O6 or Ba3Ga2O6. However, electrical conductivity of these A3Ga2O6 system oxides was lower than log (σ/S cm-1) = - 3 due to the low solubility of the aliovalent cations. On the other hand, doped perovskite type oxide of NdGaO3 and LaGaO3 exhibited a high electrical conductivity and the transference number of oxide ion was higher than 0.9 in the oxygen partial pressure range from PO2 = 1 to 10-21 atm. In particular, Ca and Mg doped NdGaO3 exhibited a high oxide ion conductivity in similar with LaGaO3 based oxide.

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U2 - 10.1016/0167-2738(96)00122-1

DO - 10.1016/0167-2738(96)00122-1

M3 - Article

AN - SCOPUS:0030182078

VL - 86-88

SP - 197

EP - 201

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - PART 1

ER -

Oxide ion conductivity in doped Ga based perovskite type oxide

Abstract

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