Oxygen Speciation in Multicomponent Silicate Glasses Using Through Bond Double Resonance NMR Spectroscopy

Sohei Sukenaga, Pierre Florian, Koji Kanehashi, Hiroyuki Shibata, Noritaka Saito, Kunihiko Nakashima, Dominique Massiot

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The description of the structure of aluminosilicate glasses is more often centered on its cationic constituents, and oxygen ions determine their connectivity, directly impacting the physical properties of those disordered materials. A very powerful approach to ascertain this short- to medium-range order is to use 17O NMR, but up to now the speciation of the chemical bonds was only ambiguously achieved for multicomponent glasses. Here, we propose to directly probe the very scarcely explored through-bond correlations using 17O{27Al} and 17O{23Na} solid-state nuclear magnetic resonance (NMR) double-resonance experiments. Our approach allows quantifying the strongly overlapping components of the 17O NMR spectra of a quaternary aluminosilicate glass. We observe a cooperative location of alkali and aluminum ions in the neighborhood of bridging oxygens, which is consistent with the modified random network model where the glass structure is composed of two regions: network structure and breakage region (i.e., channel).

Original languageEnglish
Pages (from-to)2274-2279
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume8
Issue number10
DOIs
Publication statusPublished - May 18 2017

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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