Palladium and platinum 2,4-cis-amino azetidine and related complexes

Akina Yoshizawa, Antonio Feula, Andrew G. Leach, Louise Male, John S. Fossey

Research output: Contribution to journalArticlepeer-review

Abstract

Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

Original languageEnglish
Article number211
JournalFrontiers in Chemistry
Volume6
Issue numberJUN
DOIs
Publication statusPublished - 2018
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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