TY - JOUR
T1 - Palladium-catalysed oxidation of alcohols with carbon tetrachloride, formation of 4,4,4-trichloro ketones from allylic alcohols and carbon tetrachlorid
AU - nagashima, Hideo
AU - Sato, Koji
AU - Tsuii, Jiro
PY - 1985
Y1 - 1985
N2 - Pd salts catalyse oxidation of alcohols with CCl4 in the presence of K2CO3. Primary alcohols are oxidised to esters, and secondary alcohols to ketones. CCl4 is converted to CHCl3. The reaction of allylic alcohols bearing a terminal olefinic bond with CCl4 or BrCCl3 in the presence of palladium catalyst at 110° affords 4,4,4-trichloro ketones. At 40°, simple adducts of CCl4 or BrCCl3 having a halohydrin structure are obtained, which are converted to the corresponding trichloro ketones by the catalysis of palladium. Various halohydrins are converted to ketones by Pd catalysis.
AB - Pd salts catalyse oxidation of alcohols with CCl4 in the presence of K2CO3. Primary alcohols are oxidised to esters, and secondary alcohols to ketones. CCl4 is converted to CHCl3. The reaction of allylic alcohols bearing a terminal olefinic bond with CCl4 or BrCCl3 in the presence of palladium catalyst at 110° affords 4,4,4-trichloro ketones. At 40°, simple adducts of CCl4 or BrCCl3 having a halohydrin structure are obtained, which are converted to the corresponding trichloro ketones by the catalysis of palladium. Various halohydrins are converted to ketones by Pd catalysis.
UR - http://www.scopus.com/inward/record.url?scp=0001663779&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001663779&partnerID=8YFLogxK
U2 - 10.1016/S0040-4020(01)91368-7
DO - 10.1016/S0040-4020(01)91368-7
M3 - Article
AN - SCOPUS:0001663779
SN - 0040-4020
VL - 41
SP - 5645
EP - 5651
JO - Tetrahedron
JF - Tetrahedron
IS - 23
ER -