Palladium-catalyzed γ -selective and stereospecific allyl-aryl coupling between allylic acetates and arylboronic acids

Hirohisa Ohmiya, Yusuke Makida, Tatsunori Tanaka, Masaya Sawamura

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104 Citations (Scopus)

Abstract

Allyl-aryl coupling between allylic acetates and arylboronic acids took place in the presence of catalytic amounts of Pd(OAc)2, 1,10-phenanthroline, and AgSbF6 with high #-selectivity and E/Z-selectivity. The reaction of an optically active allylic acetates with an (-stereogenic center proceeded with excellent (-to-# chirality transfer with syn-selectivity and gave the corresponding optically active allyl-aryl coupling products with a stereogenic center at the benzylic position.

Original languageEnglish
Pages (from-to)17276-17277
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number51
DOIs
Publication statusPublished - Dec 24 2008

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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