Palladium-catalyzed 1,4-addition of carboxylic acids to butadiene monoxide

Akiyuki Hamasaki, Shuhei Maruta, Aki Nakamura, Makoto Tokunaga

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3 Citations (Scopus)

Abstract

Palladium complexes catalyze the 1,4-addition of acetic acid to butadiene monoxide to give 4-hydroxybut-2-en-1-yl acetate. The highest 1,4-/1,2-addition selectivity of 18.9 was achieved. The reaction seems to proceed via a Wacker-like mechanism.

Original languageEnglish
Pages (from-to)2129-2134
Number of pages6
JournalAdvanced Synthesis and Catalysis
Volume354
Issue number11-12
DOIs
Publication statusPublished - Aug 13 2012

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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