Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates

Jiro Tsuji, Koji Sato, Hideo Nagashima

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Pd(OAc)2 combined with PPh3 is a good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates. The esters were obtained in satisfactory yields when the reaction was carried out at 50° in the presence of K2CO3 under CO pressure.

Original languageEnglish
Pages (from-to)5003-5006
Number of pages4
JournalTetrahedron
Volume41
Issue number21
DOIs
Publication statusPublished - Jan 1 1985
Externally publishedYes

Fingerprint

Addition reactions
Carbon Tetrachloride
Palladium
Alkenes
Carbon Monoxide
Alcohols
Esters
Ethanol
Pressure
Catalysts
palladium(II) acetate
potassium carbonate

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Palladium-catalyzed addition reaction of olefins, carbon tetrachloride and carbon monoxide in alcohols to give 2-alkyl-4,4,4-trichlorobutanoates. / Tsuji, Jiro; Sato, Koji; Nagashima, Hideo.

In: Tetrahedron, Vol. 41, No. 21, 01.01.1985, p. 5003-5006.

Research output: Contribution to journalArticle

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