Abstract
o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.
| Original language | English |
|---|---|
| Pages (from-to) | 3802-3803 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 129 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Apr 4 2007 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins. / Kuwano, Ryoichi; Shige, Takenori.
In: Journal of the American Chemical Society, Vol. 129, No. 13, 04.04.2007, p. 3802-3803.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins
AU - Kuwano, Ryoichi
AU - Shige, Takenori
PY - 2007/4/4
Y1 - 2007/4/4
N2 - o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.
AB - o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction provided 2- and/or 3-substituted tetralins in good yield. The catalytic reaction described here is equivalent to the [4+2] cycloaddition of o-xylylenes with dienophiles.
UR - http://www.scopus.com/inward/record.url?scp=34247124791&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34247124791&partnerID=8YFLogxK
U2 - 10.1021/ja070012l
DO - 10.1021/ja070012l
M3 - Article
C2 - 17352480
AN - SCOPUS:34247124791
VL - 129
SP - 3802
EP - 3803
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 13
ER -