Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano; Hiroki Kusano

doi:10.1246/cl.2007.528

Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano, Hiroki Kusano

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C₃H ₅)(cod)]BF₄-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

Original language	English
Pages (from-to)	528-529
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	4
DOIs	https://doi.org/10.1246/cl.2007.528
Publication status	Published - Apr 5 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2007.528

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title = "Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions",

abstract = "The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.",

author = "Ryoichi Kuwano and Hiroki Kusano",

year = "2007",

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AU - Kusano, Hiroki

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N2 - The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

AB - The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Abstract

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