Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions

Ryoichi Kuwano, Hiroki Kusano

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Abstract

The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand.

Original languageEnglish
Pages (from-to)528-529
Number of pages2
JournalChemistry Letters
Volume36
Issue number4
DOIs
Publication statusPublished - Apr 5 2007

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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