Palladium-induced pyrrolic rearrangement of a singly to a doubly N-confused [26]hexaphyrin

Sabapathi Gokulnath, Keiichi Nishimura, Motoki Toganoh, Shigeki Mori, Hiroyuki Furuta

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Abstract

A pyrrolic rearrangement reaction of singly N-confused [26]hexaphyrin mediated by PdCl2 afforded doubly N-confused [26]hexaphyrin bis(PdII) complex. The bis(PdII) complex is a rare example of an aromatic compound with definite non-degenerate HOMOs and LUMOs.

Original languageEnglish
Pages (from-to)6940-6943
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number27
DOIs
Publication statusPublished - Jul 1 2013

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

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