Palladium-induced pyrrolic rearrangement of a singly to a doubly N-confused [26]hexaphyrin

Sabapathi Gokulnath, Keiichi Nishimura, Motoki Toganoh, Shigeki Mori, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    24 Citations (Scopus)

    Abstract

    A pyrrolic rearrangement reaction of singly N-confused [26]hexaphyrin mediated by PdCl2 afforded doubly N-confused [26]hexaphyrin bis(PdII) complex. The bis(PdII) complex is a rare example of an aromatic compound with definite non-degenerate HOMOs and LUMOs.

    Original languageEnglish
    Pages (from-to)6940-6943
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume52
    Issue number27
    DOIs
    Publication statusPublished - Jul 1 2013

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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