Palladium-induced pyrrolic rearrangement of a singly to a doubly N-confused [26]hexaphyrin

Sabapathi Gokulnath, Keiichi Nishimura, Motoki Toganoh, Shigeki Mori, Hiroyuki Furuta

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A pyrrolic rearrangement reaction of singly N-confused [26]hexaphyrin mediated by PdCl2 afforded doubly N-confused [26]hexaphyrin bis(PdII) complex. The bis(PdII) complex is a rare example of an aromatic compound with definite non-degenerate HOMOs and LUMOs.

Original languageEnglish
Pages (from-to)6940-6943
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number27
DOIs
Publication statusPublished - Jul 1 2013

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Aromatic compounds
Palladium
palladium chloride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Catalysis

Cite this

Palladium-induced pyrrolic rearrangement of a singly to a doubly N-confused [26]hexaphyrin. / Gokulnath, Sabapathi; Nishimura, Keiichi; Toganoh, Motoki; Mori, Shigeki; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 52, No. 27, 01.07.2013, p. 6940-6943.

Research output: Contribution to journalArticle

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