@article{38f54164798b437882c0d112b70b6875,
title = "Paramagnetism enhancement by in situ electrochemical hole doping into a Prussian Blue thin film",
abstract = " A Prussian Blue (PB) film formed on an indium tin oxide substrate was incorporated in an electrolysis cell with an ionic-liquid midlayer (N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide) as an electrolyte. The ionic-liquid electrolysis cell mounted on a SQUID magnetometer was examined under DC bias voltage up to 4.0 V by injecting the charge carriers electrochemically into the PB film. Electrochemical hole doping increased the Fe III /Fe II ratio in the PB film, resulting in a remarkable enhancement of magnetization accompanied by quasi-reversible electrochromism. ",
author = "Mariko Noguchi and Motohiro Nakano and Soonchul Kang and Osamu Sato and Shu Seki",
note = "Funding Information: We thank Dr Naoto Matsuyama for the XPS and Prof. Hiroki Akutsu and Satoshi Yamashita (Graduate School of Science, Osaka University) for the CV. We are also grateful to Prof. Akinori Saeki (Graduate School of Engineering, Osaka University) allowing us to use the UV/vis/NIR spectrometer and to Prof. Taro Uematsu (Graduate School of Engineering, Osaka University) for help in the ICP-AES. We would like to thank Ms Yuko Fujiie for helping in the fabrication of the SQUID sample rod. This study is Contribution No. 57 from the Research Center for Structural Thermodynamics. Publisher Copyright: {\textcopyright} 2018 Royal Society of Chemistry. All Rights Reserved.",
year = "2018",
doi = "10.1039/c7qm00615b",
language = "English",
volume = "2",
pages = "1004--1008",
journal = "Materials Chemistry Frontiers",
issn = "2052-1537",
publisher = "Royal Society of Chemistry",
number = "5",
}