Pentaorgano[60]fullerene R5C60-. A water soluble hydrocarbon anion

Masaya Sawamura; Noriaki Nagahama; Motoki Toganoh; Ulrich E. Hackler; Hiroyuki Isobe; Eiichi Nakamura; Shui Quin Zhou; Benjamin Chu

doi:10.1246/cl.2000.1098

Pentaorgano[60]fullerene R₅C₆₀^-. A water soluble hydrocarbon anion

Masaya Sawamura, Noriaki Nagahama, Motoki Toganoh, Ulrich E. Hackler, Hiroyuki Isobe, Eiichi Nakamura, Shui Quin Zhou, Benjamin Chu

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A new class of hydrocarbon anions, pentaaryl- and pentamethylfullerene anions R₅C₆₀^- (R = Ph, 4-BuC₆H₄, 4-PhC₆H₄, Me) was found to be stable and soluble in water. Atomic force microscopic observation and dynamic light scattering measurements indicated that the potassium salt Ph₅C₆₀K in water forms spherical aggregates with an averaged radius of about 17 nm.

Original language	English
Pages (from-to)	1098-1099
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2000.1098
Publication status	Published - 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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title = "Pentaorgano[60]fullerene R5C60-. A water soluble hydrocarbon anion",

abstract = "A new class of hydrocarbon anions, pentaaryl- and pentamethylfullerene anions R5C60- (R = Ph, 4-BuC6H4, 4-PhC6H4, Me) was found to be stable and soluble in water. Atomic force microscopic observation and dynamic light scattering measurements indicated that the potassium salt Ph5C60K in water forms spherical aggregates with an averaged radius of about 17 nm.",

author = "Masaya Sawamura and Noriaki Nagahama and Motoki Toganoh and Hackler, {Ulrich E.} and Hiroyuki Isobe and Eiichi Nakamura and Zhou, {Shui Quin} and Benjamin Chu",

year = "2000",

doi = "10.1246/cl.2000.1098",

language = "English",

pages = "1098--1099",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - Pentaorgano[60]fullerene R5C60-. A water soluble hydrocarbon anion

AU - Sawamura, Masaya

AU - Nagahama, Noriaki

AU - Toganoh, Motoki

AU - Hackler, Ulrich E.

AU - Isobe, Hiroyuki

AU - Nakamura, Eiichi

AU - Zhou, Shui Quin

AU - Chu, Benjamin

PY - 2000

Y1 - 2000

N2 - A new class of hydrocarbon anions, pentaaryl- and pentamethylfullerene anions R5C60- (R = Ph, 4-BuC6H4, 4-PhC6H4, Me) was found to be stable and soluble in water. Atomic force microscopic observation and dynamic light scattering measurements indicated that the potassium salt Ph5C60K in water forms spherical aggregates with an averaged radius of about 17 nm.

AB - A new class of hydrocarbon anions, pentaaryl- and pentamethylfullerene anions R5C60- (R = Ph, 4-BuC6H4, 4-PhC6H4, Me) was found to be stable and soluble in water. Atomic force microscopic observation and dynamic light scattering measurements indicated that the potassium salt Ph5C60K in water forms spherical aggregates with an averaged radius of about 17 nm.

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U2 - 10.1246/cl.2000.1098

DO - 10.1246/cl.2000.1098

M3 - Article

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EP - 1099

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 9

ER -

Pentaorgano[60]fullerene R₅C₆₀^-. A water soluble hydrocarbon anion

Abstract

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