TY - GEN
T1 - Performance of SOFC power unit assisted by paper-structured catalyst
AU - Shiratori, Y.
AU - Sakamoto, M.
AU - Tran, Q. T.
AU - Uchiyama, Y.
AU - Uchiyama, N.
N1 - Publisher Copyright:
© The Electrochemical Society.
PY - 2015
Y1 - 2015
N2 - Paper-structured catalyst (PSC) is a flexible catalyst material composed of inorganic fiber network loaded with metal catalyst which can be applied into cell stack to assist hydrocarbon reforming. Catalytic performance of PSC was considerably improved by the dispersion of Mg-Al hydrotalcite (HT) in the inorganic fiber network because of the formation of fine Ni particles and suppression of Ni loading on the inorganic fiber (SiO2-Al2O3) to cause coking. High temperature SOFCs can convert chemical energy of a fuel directly to electricity even in the feed of low calorie gas. The use of engine-exhaust, which contains unburned hydrocarbons, H2 and CO, as a fuel for SOFC is promising idea. Recently, a compact SOFC unit operated by the direct feed of engine-exhaust was developed by Atsumitec Co., Ltd. However, performance of the unit can easily deteriorate, unless the fuel is homogeneously supplied into the unit in which several numbers of stacks were arrayed. This study demonstrated that insertion of the HT-dispersed PSC into the real SOFC stack led to large increase in the unit performance because PSCs can boost up the output power of stacks placed at the positions where fuel is not well supplied.
AB - Paper-structured catalyst (PSC) is a flexible catalyst material composed of inorganic fiber network loaded with metal catalyst which can be applied into cell stack to assist hydrocarbon reforming. Catalytic performance of PSC was considerably improved by the dispersion of Mg-Al hydrotalcite (HT) in the inorganic fiber network because of the formation of fine Ni particles and suppression of Ni loading on the inorganic fiber (SiO2-Al2O3) to cause coking. High temperature SOFCs can convert chemical energy of a fuel directly to electricity even in the feed of low calorie gas. The use of engine-exhaust, which contains unburned hydrocarbons, H2 and CO, as a fuel for SOFC is promising idea. Recently, a compact SOFC unit operated by the direct feed of engine-exhaust was developed by Atsumitec Co., Ltd. However, performance of the unit can easily deteriorate, unless the fuel is homogeneously supplied into the unit in which several numbers of stacks were arrayed. This study demonstrated that insertion of the HT-dispersed PSC into the real SOFC stack led to large increase in the unit performance because PSCs can boost up the output power of stacks placed at the positions where fuel is not well supplied.
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U2 - 10.1149/06801.2783ecst
DO - 10.1149/06801.2783ecst
M3 - Conference contribution
AN - SCOPUS:84938796569
T3 - ECS Transactions
SP - 2783
EP - 2788
BT - Solid Oxide Fuel Cells 14, SOFC 2015
A2 - Eguchi, K.
A2 - Singhal, S. C.
PB - Electrochemical Society Inc.
T2 - 14th International Symposium on Solid Oxide Fuel Cells, SOFC 2015; held as part of the Electrochemical Society, ECS Conference on Electrochemical Energy Conversion and Storage
Y2 - 26 July 2015 through 31 July 2015
ER -