Phase diagram of organic superconductor κ-(ET)2Cu[N(CN)2]Br as it is seen from isothermal resistance relaxation

M. A. Tanatar, T. Ishiguro, H. Ito, T. Kondo, G. Saito

Research output: Contribution to journalConference article

4 Citations (Scopus)

Abstract

Phase diagram of κ-(ET)2Cu[N(CN)2]Br superconductor was studied by resistance measurements of structural relaxation kinetics and properties of nonequilibrium phases after isochronous annealing. We show, that (1) the activation energy of the lattice relaxation time below 100 K corresponds well to the potential barrier heights for ET molecule conformation; (2) the shape of the diagram corresponds to that of the ethylene ordering phenomena with superstructure formation; (3) the known anomalies of the electronic properties of the salt, namely resistance hump at around 100 K and pseudogap behavior at 60 K correspond to upper and lower hysteresis branches of the ethylene transformation, while the main second order phase transition proceeds at 80 K; (4) the state that comes our of the transformation is not an ordered state, but rather contains superstructure interacting with the Fermi surface and causing its partial destruction. We discuss these findings, together with high superconducting TC and negative isotope effect as indications of crucial soft lattice contribution to the superconducting properties in organics.

Original languageEnglish
Pages (from-to)1849-1852
Number of pages4
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - Jun 24 1999
EventProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
Duration: Jul 12 1998Jul 18 1998

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organic superconductors
Superconducting materials
Phase diagrams
Ethylene
phase diagrams
Structural relaxation
Fermi surface
ethylene
Isotopes
Electronic properties
Relaxation time
Hysteresis
Conformations
Activation energy
Salts
Phase transitions
Annealing
isotope effect
Molecules
Kinetics

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Phase diagram of organic superconductor κ-(ET)2Cu[N(CN)2]Br as it is seen from isothermal resistance relaxation. / Tanatar, M. A.; Ishiguro, T.; Ito, H.; Kondo, T.; Saito, G.

In: Synthetic Metals, Vol. 103, No. 1-3, 24.06.1999, p. 1849-1852.

Research output: Contribution to journalConference article

Tanatar, M. A. ; Ishiguro, T. ; Ito, H. ; Kondo, T. ; Saito, G. / Phase diagram of organic superconductor κ-(ET)2Cu[N(CN)2]Br as it is seen from isothermal resistance relaxation. In: Synthetic Metals. 1999 ; Vol. 103, No. 1-3. pp. 1849-1852.
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abstract = "Phase diagram of κ-(ET)2Cu[N(CN)2]Br superconductor was studied by resistance measurements of structural relaxation kinetics and properties of nonequilibrium phases after isochronous annealing. We show, that (1) the activation energy of the lattice relaxation time below 100 K corresponds well to the potential barrier heights for ET molecule conformation; (2) the shape of the diagram corresponds to that of the ethylene ordering phenomena with superstructure formation; (3) the known anomalies of the electronic properties of the salt, namely resistance hump at around 100 K and pseudogap behavior at 60 K correspond to upper and lower hysteresis branches of the ethylene transformation, while the main second order phase transition proceeds at 80 K; (4) the state that comes our of the transformation is not an ordered state, but rather contains superstructure interacting with the Fermi surface and causing its partial destruction. We discuss these findings, together with high superconducting TC and negative isotope effect as indications of crucial soft lattice contribution to the superconducting properties in organics.",
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AU - Tanatar, M. A.

AU - Ishiguro, T.

AU - Ito, H.

AU - Kondo, T.

AU - Saito, G.

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N2 - Phase diagram of κ-(ET)2Cu[N(CN)2]Br superconductor was studied by resistance measurements of structural relaxation kinetics and properties of nonequilibrium phases after isochronous annealing. We show, that (1) the activation energy of the lattice relaxation time below 100 K corresponds well to the potential barrier heights for ET molecule conformation; (2) the shape of the diagram corresponds to that of the ethylene ordering phenomena with superstructure formation; (3) the known anomalies of the electronic properties of the salt, namely resistance hump at around 100 K and pseudogap behavior at 60 K correspond to upper and lower hysteresis branches of the ethylene transformation, while the main second order phase transition proceeds at 80 K; (4) the state that comes our of the transformation is not an ordered state, but rather contains superstructure interacting with the Fermi surface and causing its partial destruction. We discuss these findings, together with high superconducting TC and negative isotope effect as indications of crucial soft lattice contribution to the superconducting properties in organics.

AB - Phase diagram of κ-(ET)2Cu[N(CN)2]Br superconductor was studied by resistance measurements of structural relaxation kinetics and properties of nonequilibrium phases after isochronous annealing. We show, that (1) the activation energy of the lattice relaxation time below 100 K corresponds well to the potential barrier heights for ET molecule conformation; (2) the shape of the diagram corresponds to that of the ethylene ordering phenomena with superstructure formation; (3) the known anomalies of the electronic properties of the salt, namely resistance hump at around 100 K and pseudogap behavior at 60 K correspond to upper and lower hysteresis branches of the ethylene transformation, while the main second order phase transition proceeds at 80 K; (4) the state that comes our of the transformation is not an ordered state, but rather contains superstructure interacting with the Fermi surface and causing its partial destruction. We discuss these findings, together with high superconducting TC and negative isotope effect as indications of crucial soft lattice contribution to the superconducting properties in organics.

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