Abstract
In general, transition metal-doped La0.6Sr0.4FeO3 (LSF) has been used as a cathode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) because of its high mixed electronic−ionic conductivity and catalytic properties. Recently, some research groups have been investigating the doped LSF as an anode material. In this study, we evaluated the influence of dopant in LSF on anodic properties of LSF in SOFCs. Whereas Mn-doped LSF showed typical perovskite oxide structure even after reduction in hydrogen at high temperature, the LSF and Co-doped LSF exhibited phase transition partially to LaSrFeO4 and exsolution of metal particles after reduction. The phase transition and metal exsolution occurred at temperature higher than 1008 K in a reducing atmosphere. Despite the partial phase transition, the cell using Co-doped LSF anode exhibited fairly high power density of 1.33 W/cm2 at 1173 K with the lowest polarization resistance. These results may originate from the high oxygen-ion conductivity of LaSrFeO4–La(Sr)Fe(Co)O3 and the high hydrogen oxidation property of the Co–Fe particles on ceramic anode surface.
| Original language | English |
|---|---|
| Pages (from-to) | 29641-29647 |
| Number of pages | 7 |
| Journal | International Journal of Hydrogen Energy |
| Volume | 44 |
| Issue number | 56 |
| DOIs | |
| Publication status | Published - Nov 12 2019 |
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All Science Journal Classification (ASJC) codes
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Condensed Matter Physics
- Energy Engineering and Power Technology
Cite this
Phase transition of doped LaFeO3 anode in reducing atmosphere and their power generation property in intermediate temperature solid oxide fuel cell. / Ju, Young Wan; Lee, Sang Won; Kang, Byeong Su; Kim, Hack Ho; Ishihara, Tatsumi.
In: International Journal of Hydrogen Energy, Vol. 44, No. 56, 12.11.2019, p. 29641-29647.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Phase transition of doped LaFeO3 anode in reducing atmosphere and their power generation property in intermediate temperature solid oxide fuel cell
AU - Ju, Young Wan
AU - Lee, Sang Won
AU - Kang, Byeong Su
AU - Kim, Hack Ho
AU - Ishihara, Tatsumi
PY - 2019/11/12
Y1 - 2019/11/12
N2 - In general, transition metal-doped La0.6Sr0.4FeO3 (LSF) has been used as a cathode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) because of its high mixed electronic−ionic conductivity and catalytic properties. Recently, some research groups have been investigating the doped LSF as an anode material. In this study, we evaluated the influence of dopant in LSF on anodic properties of LSF in SOFCs. Whereas Mn-doped LSF showed typical perovskite oxide structure even after reduction in hydrogen at high temperature, the LSF and Co-doped LSF exhibited phase transition partially to LaSrFeO4 and exsolution of metal particles after reduction. The phase transition and metal exsolution occurred at temperature higher than 1008 K in a reducing atmosphere. Despite the partial phase transition, the cell using Co-doped LSF anode exhibited fairly high power density of 1.33 W/cm2 at 1173 K with the lowest polarization resistance. These results may originate from the high oxygen-ion conductivity of LaSrFeO4–La(Sr)Fe(Co)O3 and the high hydrogen oxidation property of the Co–Fe particles on ceramic anode surface.
AB - In general, transition metal-doped La0.6Sr0.4FeO3 (LSF) has been used as a cathode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) because of its high mixed electronic−ionic conductivity and catalytic properties. Recently, some research groups have been investigating the doped LSF as an anode material. In this study, we evaluated the influence of dopant in LSF on anodic properties of LSF in SOFCs. Whereas Mn-doped LSF showed typical perovskite oxide structure even after reduction in hydrogen at high temperature, the LSF and Co-doped LSF exhibited phase transition partially to LaSrFeO4 and exsolution of metal particles after reduction. The phase transition and metal exsolution occurred at temperature higher than 1008 K in a reducing atmosphere. Despite the partial phase transition, the cell using Co-doped LSF anode exhibited fairly high power density of 1.33 W/cm2 at 1173 K with the lowest polarization resistance. These results may originate from the high oxygen-ion conductivity of LaSrFeO4–La(Sr)Fe(Co)O3 and the high hydrogen oxidation property of the Co–Fe particles on ceramic anode surface.
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U2 - 10.1016/j.ijhydene.2019.05.052
DO - 10.1016/j.ijhydene.2019.05.052
M3 - Article
AN - SCOPUS:85066263843
VL - 44
SP - 29641
EP - 29647
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 56
ER -