Phenolate-bridged A2B-type subporphyrin dimer

Shoma Hirokawa, Shigeki Mori, Nagao Kobayashi, Soji Shimizu

    Research output: Contribution to journalArticlepeer-review

    Abstract

    An ether cleavage reaction of A2B-type subporphyrin bearing an ortho-anisyl substituent afforded a phenolate-bridged dimer. A head-to-tail structure of the dimer was unambiguously elucidated by single crystal X-ray diffraction analysis. UV-vis absorption and magnetic circular dichroism spectra indicated a minor interaction between the subporphyrin chromophores. Density functional theory calculations provided a detailed insight into the electronic structures of the subporphyrin dimer.

    Original languageEnglish
    JournalJournal of Porphyrins and Phthalocyanines
    DOIs
    Publication statusAccepted/In press - 2021

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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